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Chemistry / Organic Chemistry 2 / Chapter 11 / Problem 11.24

Organic Chemistry | 2nd Edition | ISBN: 9781118454312 | Authors: David R. Klein

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Rank each group of radicals in order of increasing

Chapter 11, Problem 11.24

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QUESTION:

Rank each group of radicals in order of increasing stability: (a) (b)

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QUESTION:

Rank each group of radicals in order of increasing stability: (a) (b)

ANSWER:

Step 1 of 2

(a)

These radicals all contain cyclic alkanes in nature, with one of them including an allylic radical.

The order of the stability of the radicals is as follows:

allylic > 3° > 2° > 1° > methyl

Following the stability order given above, ranking of these radicals in order of increasing stability would be as follows: 4 (primary radical) < 2 (secondary radical) < 1 (tertiary radical) < 3 (allylic radical)

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