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Name each of the following aldohexoses: C H OH HO H H OH H

Chapter 24, Problem 24.44

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QUESTION:

Name each of the following aldohexoses: C H OH HO H H OH H OH CH2OH H O (a) C HO H HO H H OH H OH CH2OH H O (b) C H OH HO H HO H H OH CH2OH H O (c) C HO H H OH HO H HO H CH2OH H O (d)

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QUESTION:

Name each of the following aldohexoses: C H OH HO H H OH H OH CH2OH H O (a) C HO H HO H H OH H OH CH2OH H O (b) C H OH HO H HO H H OH CH2OH H O (c) C HO H H OH HO H HO H CH2OH H O (d)

ANSWER:

Step 1 of 5

There is no systematic way of naming simple monosaccharides such as this, other than to assign them a D or L configuration.

The base name must simply be memorized, based on the arrangement of hydroxyl groups. Recall that to determine if a sugar is D or L, we need to look at the chiral carbon furthest from the carbonyl group (when drawn in a Fischer projection). If the hydroxyl group is pointing to the right, then it is a D sugar; if the hydroxyl group is pointing to the left, then it is an L sugar.

With these guidelines in place, we can begin to examine the structures we have been given.

 

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