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A mixture of amino acids was treated with ninhydrin, and

Chapter 25, Problem 25.55

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QUESTION:

A mixture of amino acids was treated with ninhydrin, and the following aldehydes were all observed in the product mixture: S H O O H H H O (a) Identify the structure and name all three amino acids in the starting mixture. (b) In addition to the aldehydes, a purple-colored product is obtained. Draw the structure of the compound responsible for the purple color. (c) Describe the origin of the purple color.

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QUESTION:

A mixture of amino acids was treated with ninhydrin, and the following aldehydes were all observed in the product mixture: S H O O H H H O (a) Identify the structure and name all three amino acids in the starting mixture. (b) In addition to the aldehydes, a purple-colored product is obtained. Draw the structure of the compound responsible for the purple color. (c) Describe the origin of the purple color.

ANSWER:

Step 1 of 4

In this multi-part exercise, we’re shown the structures of a mixture of amino acids that are treated with ninhydrin. Following reaction, the following aldehydes were all observed in the product mixture:

     

Recall that ninhydrin is an organic reagent designed to react with amino acids (under basic conditions) to form a purple colored tetracyclic product. It can be used as a test for amino acids, making it useful in forensic chemistry. Other reaction products include water, carbon dioxide, and an aldehyde based on the nature of the starting amino acid. The R chain on the  position of the amino acid becomes the R chain of the aldehyde after reaction with ninhydrin.

The exercise asks us a series of questions about this reaction

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