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Solved: Table 10.3 shows that the van der Waals b

Chapter , Problem 10.98

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QUESTION:

Table 10.3 shows that the van der Waals b parameter has units of L/mol. This means that we can calculate the sizes of atoms or molecules from the b parameter. Refer back to the discussion in Section 7.3. Is the van der Waals radius we calculate from the b parameter of Table 10.3 more closely associated with the bonding or nonbonding atomic radius discussed there? Explain.

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QUESTION:

Table 10.3 shows that the van der Waals b parameter has units of L/mol. This means that we can calculate the sizes of atoms or molecules from the b parameter. Refer back to the discussion in Section 7.3. Is the van der Waals radius we calculate from the b parameter of Table 10.3 more closely associated with the bonding or nonbonding atomic radius discussed there? Explain.

ANSWER:

Problem 10.98Table 10.3 shows that the van der Waals b parameter has units of L/mol. This means that wecan calculate the sizes of atoms or molecules from the b parameter. Refer back to thediscussion in Section 7.3. Is the van der Waals radius we calculate from the b parameter ofTable 10.3 more closely associated with the bonding or nonbonding atomic radius discussedthere Explain. Step-by-step solution Step 1 of 2 The van der Waals equation is given as: 2 (P + n 2) (V nb) = nRT VHere,P is the pressure,V is the volume,N is the number of moles,R is the gas constant,T is the temperature and,a and b are the van der Waals constant. n aWhile 2 accounts for the attractive forces between molecules, nb accounts for small finite Vvolume occupied by the molecules.The value of b is determined by the van der Waals radius.

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