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True or false: (a) CBr4 is more volatile than CCl4. (b)

Chapter , Problem 11.52

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QUESTION:

True or false:
(a) \(CBr_4\) is more volatile than \(CCl_4\).
(b) \(CBr_4\) has a higher boiling point than \(CCl_4\).
(c) \(CBr_4\) has weaker intermolecular forces than \(CCl_4\).
(d) \(CBr_4\) has a higher vapor pressure at the same temperature
than \(CCl_4\).

Questions & Answers

QUESTION:

True or false:
(a) \(CBr_4\) is more volatile than \(CCl_4\).
(b) \(CBr_4\) has a higher boiling point than \(CCl_4\).
(c) \(CBr_4\) has weaker intermolecular forces than \(CCl_4\).
(d) \(CBr_4\) has a higher vapor pressure at the same temperature
than \(CCl_4\).

ANSWER:

Step 1 of 4

(a) \(CBr_4\) is more volatile than \(CCl_4\). 

The above statement is false.

The polarizability of \(CBr_4\) is greater than  \(CCl_4\). It is known that as the greater the polarizability factor, stronger the dispersion forces hence molecules do not easily go to vapor state. Hence \(CBr_4\) is less volatile than \(CCl_4\). 

 

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