The reaction 2 ClO21aq2 + 2 OH- 1aq2 ClO3 - 1aq2 + ClO2 -

Chapter , Problem 14.34

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The reaction 2 ClO21aq2 + 2 OH- 1aq2 ClO3 - 1aq2 + ClO2 - 1aq2 + H2O1l2 was studied with the following results: Experiment 1Clo22 1M2 3oh4 1M2 initial Rate 1M,s2 1 0.060 0.030 0.0248 2 0.020 0.030 0.00276 3 0.020 0.090 0.00828 (a) Determine the rate law for the reaction. (b) Calculate the rate constant with proper units. (c) Calculate the rate when 3ClO24 = 0.100 M and 3OH- 4 = 0.050 M.

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