The enzyme urease catalyzes the reaction of urea,

Chapter , Problem 14.86

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The enzyme urease catalyzes the reaction of urea, 1NH2CONH22, with water to produce carbon dioxide and ammonia. In water, without the enzyme, the reaction proceeds with a first-order rate constant of 4.15 * 10-5 s -1 at 100 C. In the presence of the enzyme in water, the reaction proceeds with a rate constant of 3.4 * 104 s -1 at 21 C. (a) Write out the balanced equation for the reaction catalyzed by urease. (b) If the rate of the catalyzed reaction were the same at 100 C as it is at 21 C, what would be the difference in the activation energy between the catalyzed and uncatalyzed reactions? (c) In actuality, what would you expect for the rate of the catalyzed reaction at 100 C as compared to that at 21 C? (d) On the basis of parts (c) and (d), what can you conclude about the difference in activation energies for the catalyzed and uncatalyzed reactions?