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A mixture of 0.2000 mol of CO2, 0.1000 mol of H2, and

Chapter , Problem 15.37

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QUESTION:

A mixture of 0.2000 mol of \(CO_2\), 0.1000 mol of \(H_2\), and 0.1600 mol of \(H_2O\) is placed in a 2.000-L vessel. The following equilibrium is established at 500 K:

\(\mathrm{CO}_{2}(g)+\mathrm{H}_{2}(g) \rightleftharpoons \mathrm{CO}(g)+\mathrm{H}_{2} \mathrm{O}(g)\)

(a) Calculate the initial partial pressures of \(CO_2\), \(H_2\), and \(H_2O\).

(b) At equilibrium \(P_{H_2O}\) = 3.51 atm. Calculate the equilibrium partial pressures of \(CO_2\), \(H_2\), and CO.

(c) Calculate \(K_p\) for the reaction.

(d) Calculate \(K_c\) for the reaction

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QUESTION:

A mixture of 0.2000 mol of \(CO_2\), 0.1000 mol of \(H_2\), and 0.1600 mol of \(H_2O\) is placed in a 2.000-L vessel. The following equilibrium is established at 500 K:

\(\mathrm{CO}_{2}(g)+\mathrm{H}_{2}(g) \rightleftharpoons \mathrm{CO}(g)+\mathrm{H}_{2} \mathrm{O}(g)\)

(a) Calculate the initial partial pressures of \(CO_2\), \(H_2\), and \(H_2O\).

(b) At equilibrium \(P_{H_2O}\) = 3.51 atm. Calculate the equilibrium partial pressures of \(CO_2\), \(H_2\), and CO.

(c) Calculate \(K_p\) for the reaction.

(d) Calculate \(K_c\) for the reaction

ANSWER:

Step 1 of 5 

Given chemical equation is:

\(\mathrm{CO}_{2}(\mathrm{g})+\mathrm{H}_{2}(\mathrm{g}) \rightleftharpoons \mathrm{CO}(\mathrm{g})+\mathrm{H}_{2} \mathrm{O}(\mathrm{g})\)

Composition of mixture of gases at 500 K is:

\(\mathrm{CO}_{2}\) : 0.200 mol

\(\mathrm{H}_{2}\) : 0.1000 mol

\(\mathrm{H}_{2} \mathrm{O}\) : 0.1600 mol

Volume of flask = 2.000 L

 

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