A mixture of 1773 g of water and 227 g of ice is in an

Chapter , Problem 15

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A mixture of 1773 g of water and 227 g of ice is in an initial equilibrium state at 0.000-C. The mixture is then, in a reversible process, brought to a second equilibrium state where the waterice ratio, by mass, is 1.00!1.00 at 0.000-C. (a) Calculate the entropy change of the system during this process. (The heat of fusion for water is 333 kJ/kg.) (b) The system is then returned to the initial equilibrium state in an irreversible process (say, by using a Bunsen burner). Calculate the entropy change of the system during this process. (c) Are your answers consistent with the second law of thermodynamics?

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