A solution of Na2SO4 is added dropwise to a solution that

Chapter , Problem 17.74

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A solution of Na2SO4 is added dropwise to a solution that is 0.010 M in Ba 2 + and 0.010 M in Sr 2 + . (a) What concentration of SO4 2 - is necessary to begin precipitation? (Neglect volume changes. BaSO4: Ksp = 1.1 * 10-10 ; SrSO4: Ksp = 3.2 * 10-7 .) (b) Which cation precipitates first? (c) What is the concentration of SO4 2 - when the second cation begins to precipitate?

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