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Reactions in which a substance decomposes by losing CO are

Chapter , Problem 19.70

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QUESTION:

Reactions in which a substance decomposes by losing CO are called decarbonylation reactions. The decarbonylation of acetic acid proceeds according to: CH3COOH1l2 CH3OH1g2 + CO1g2 By using data from Appendix C, calculate the minimum temperature at which this process will be spontaneous under standard conditions. Assume that H and S do not vary with temperature.

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QUESTION:

Reactions in which a substance decomposes by losing CO are called decarbonylation reactions. The decarbonylation of acetic acid proceeds according to: CH3COOH1l2 CH3OH1g2 + CO1g2 By using data from Appendix C, calculate the minimum temperature at which this process will be spontaneous under standard conditions. Assume that H and S do not vary with temperature.

ANSWER:

Problem 19.70

Reactions in which a substance decomposes by losing CO are called decarbonylation reactions. The decarbonylation of acetic acid proceeds according to:

By using data from Appendix C, calculate the minimum temperature at which this process will be spontaneous under standard conditions. Assume that H and S do not vary with temperature.

                                                      Step by step solution

Step 1 of 2

The given reaction is as follows.

= +175.3 kJ / mol

=275.7 J / mol . K

=0.276 kJ / mol . K

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