A voltaic cell is constructed with two silversilver

Chapter , Problem 20.70

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A voltaic cell is constructed with two silversilver chloride electrodes, each of which is based on the following half-reaction: AgCl1s2 + e- Ag1s2 + Cl -1aq2 The two half-cells have 3Cl -4 = 0.0150 M and 3Cl -4 = 2.55 M, respectively. (a) Which electrode is the cathode of the cell? (b) What is the standard emf of the cell? (c) What is the cell emf for the concentrations given? (d) For each electrode, predict whether 3Cl -4 will increase, decrease, or stay the same as the cell operates.

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