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In each of the following sets, arrange the compounds in order of increasing acidity

Organic Chemistry | 6th Edition | ISBN: 9781936221349 | Authors: Marc Loudon, Jim Parise ISBN: 9781936221349 461

Solution for problem 10.3 Chapter 10.1

Organic Chemistry | 6th Edition

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Organic Chemistry | 6th Edition | ISBN: 9781936221349 | Authors: Marc Loudon, Jim Parise

Organic Chemistry | 6th Edition

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Problem 10.3

In each of the following sets, arrange the compounds in order of increasing acidity (decreasing pKa). Explain your choices. (a) ClCH2CH2OH, Cl2CHCH2OH, Cl(CH2)3OH (b) ClCH2CH2SH, ClCH2CH2OH, CH3CH2OH (c) CH3CH2CH2CH2OH, CH3OCH2CH2OH

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Lecture Saturday,January30,2016 7:08PM 1/6 Inorderforamoleculetobepolar: • Polarbonds • Dipolemomentdoesnotcancelout § ChecktheLewisStructureforthis Thestructureoficemakesitlessdensethanwater - Morespacebetweenmolecules Intermolecularforcesareeasiertobreakthanintramolecularforces. Isotropic:propertiesthesameinalldirections SurfaceTension: layerofmoleculesonsurfacebehavedifferentlythaninteriorbecauseofcohesivenessonsurface whichhasanetpullontheliquid. - Ifaliquidbeadsonasurface,andtheliquidispolar,thesurfacemust-polar. ○ Surfacepolaritycausesattractionofpolarliquidcausingtheliquidtospreadevenly. Viscosity: resistanceofliquidtoflow. -

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Textbook: Organic Chemistry
Edition: 6
Author: Marc Loudon, Jim Parise
ISBN: 9781936221349

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In each of the following sets, arrange the compounds in order of increasing acidity