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When tert-butyl alcohol is treated with H2 18O (water containing the heavy oxygen

Organic Chemistry | 6th Edition | ISBN: 9781936221349 | Authors: Marc Loudon, Jim Parise

Problem 10.45 Chapter 10

Organic Chemistry | 6th Edition

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Organic Chemistry | 6th Edition | ISBN: 9781936221349 | Authors: Marc Loudon, Jim Parise

Organic Chemistry | 6th Edition

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Problem 10.45

When tert-butyl alcohol is treated with H2 18O (water containing the heavy oxygen isotope 18O) in the presence of a small amount of acid, and the tert-butyl alcohol is re-isolated, it is found to contain 18O. Write a curvedarrow mechanism consisting of Brnsted acidbase reactions, Lewis acidbase associations, and Lewis acidbase dissociations that explains how the isotope is incorporated into the alcohol.

Step-by-Step Solution:
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\l *..-\--1,'"ir"ri-\t-qi'.,* i:i'.q*,;: :- -i1l*- t*Lro-"t filv'r*'"3,\1ufe'. f{-(* 6.,-\4;.;-ri3 ' j-.,,-r'hc. \V\ a. w\r.\r r..\e & Y sr*-r v}"(k.ei.\{;vr ---\- [', IVH_...

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Chapter 10, Problem 10.45 is Solved
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Textbook: Organic Chemistry
Edition: 6
Author: Marc Loudon, Jim Parise
ISBN: 9781936221349

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When tert-butyl alcohol is treated with H2 18O (water containing the heavy oxygen

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