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a) Verify that the following compound meets the Hckel criteria for aromaticity. (b) The

Organic Chemistry | 6th Edition | ISBN: 9781936221349 | Authors: Marc Loudon, Jim Parise ISBN: 9781936221349 461

Solution for problem 16.5 Chapter 16.3

Organic Chemistry | 6th Edition

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Organic Chemistry | 6th Edition | ISBN: 9781936221349 | Authors: Marc Loudon, Jim Parise

Organic Chemistry | 6th Edition

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Problem 16.5

a) Verify that the following compound meets the Hckel criteria for aromaticity. (b) The NMR spectrum of this compound consists of two sets of multiplets: one at d 9.28 and the other at d (22.99); the latter resonance is at 3 ppm lower chemical shift than that of TMSthat is, to the right of TMS in a conventional NMR spectrum. The relative integral of the two resonances is 2 : 1, respectively. Assign the two sets of resonances, and explain why their chemical shifts are so different; in particular, explain why one of the chemical shifts is so small. (Hint: Look carefully at the direction of the induced field in Fig. 16.2.)

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Brown 1 Kylie Brown January 17/19, 2018 Chemistry 109 Cappuccio Chapter 1. Particles of Matter: Measurements and the tools of science ➔ 1.1. How and why ◆ Learning objective: To understand the macroscopic and the particulate view. ➔ 1.2. Matter ◆ Learning Objective: To classify matter and define key terms. ➔ Vocabulary: ◆ Matter:...

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Chapter 16.3, Problem 16.5 is Solved
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Textbook: Organic Chemistry
Edition: 6
Author: Marc Loudon, Jim Parise
ISBN: 9781936221349

This textbook survival guide was created for the textbook: Organic Chemistry, edition: 6. This full solution covers the following key subjects: . This expansive textbook survival guide covers 239 chapters, and 1693 solutions. Since the solution to 16.5 from 16.3 chapter was answered, more than 232 students have viewed the full step-by-step answer. The answer to “a) Verify that the following compound meets the Hckel criteria for aromaticity. (b) The NMR spectrum of this compound consists of two sets of multiplets: one at d 9.28 and the other at d (22.99); the latter resonance is at 3 ppm lower chemical shift than that of TMSthat is, to the right of TMS in a conventional NMR spectrum. The relative integral of the two resonances is 2 : 1, respectively. Assign the two sets of resonances, and explain why their chemical shifts are so different; in particular, explain why one of the chemical shifts is so small. (Hint: Look carefully at the direction of the induced field in Fig. 16.2.)” is broken down into a number of easy to follow steps, and 112 words. Organic Chemistry was written by and is associated to the ISBN: 9781936221349. The full step-by-step solution to problem: 16.5 from chapter: 16.3 was answered by , our top Chemistry solution expert on 03/16/18, 03:35PM.

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