- 6.9SE.1PE: Electron Configurations from the Periodic Table (a) Based on its po...
- 6.9SE.2PE: Electron Configurations from the Periodic Table (a) Based on its po...
Solutions for Chapter 6.9SE: Chemistry: A Molecular Approach 3rd Edition
Full solutions for Chemistry: A Molecular Approach | 3rd Edition
A two-step process that achieves Markovnikov addition of an alcohol (H and OR) across an alkene. The product of this process is an ether.
amino acid residue
The individual repeating units in a polypeptide chain or protein.
A compound containing a Br group and a hydroxyl group (OH) on adjacent carbon atoms.
A microcrystalline form of carbon. (Section 22.9)
An alkane whose structure contains a ring.
A type of magnetism that causes a substance with no unpaired electrons to be weakly repelled from a magnetic field. (Section 9.8)
electrophilic aromatic substitution
A substitution reaction in which an aromatic proton is replaced by an electrophile and the aromatic moiety is preserved.
Ground-state electron confi guration
The lowest-energy electron confi guration for an atom or molecule.
Heterolytic bond cleavage
Cleavage of a bond so that one fragment retains both electrons and the other retains none.
Points in a crystal all of which have identical environments. (Section 12.2)
limiting reactant (limiting reagent)
The reactant present in the smallest stoichiometric quantity in a mixture of reactants; the amount of product that can form is limited by the complete consumption of the limiting reactant. (Section 3.7)
A reagent used for allylic bromination to avoid a competing reaction in which bromine adds across the p bond.
A form of isomerism in which the two forms of a compound (stereoisomers) are nonsuperimposable mirror images. (Section 23.4)
The conjugate base of phenol or a substituted phenol.
Changes (such as a phase change) that occur with no change in chemical composition. (Section 1.3)
A polymer containing the !NHCO2! group as a repeating unit
Replacing this hydrogen by deuterium gives a chiral center with an S confi guration
A reaction that has a rate equation in which the sum of all exponents is two.
Shielding in NMR
Also called diamagnetic shielding; the term refers to the reduction in magnetic fi eld strength experienced by a nucleus underneath electron density induced to circulate when the molecule is placed in a strong magnetic fi eld.
Groups that strongy deactivate an aromatic ring toward electrophilic aromatic substitution, thereby significantly decreasing the rate of the reaction.