Chemical Principles 8th Edition - Solutions by Chapter

The conjugate base of an alcohol.

A radical reaction that achieves installation of a bromine atom at an allylic position.

The C1 position of the cyclic hemiacetal of an aldose or the C2 position of the cyclic hemiacetal of a ketose.

Reduction of the C"O group of an aldehyde or ketone to a CH2 group using Zn(Hg) and HCl

Properties of solutions that depend on the number of solute particles in solution and not on the nature of the solute particles. (12.6)

A phenomenon observed most commonly for nonequivalent protons connected to adjacent carbon atoms in which the multiplicity of each signal is affected by the other.

The structure for DNA that involves the winding of two DNA polynucleotide chains together in a helical arrangement. The two strands of the double helix are complementary in that the organic bases on the two strands are paired for optimal hydrogen bond interaction. (Section 24.10)

A cyclic ether containing a three-membered ring system. Also called an oxirane (also see Sect. 14.7).

A reaction in which a proton and a hydroxyl group (OH) are added across a p bond.

A type of isomerism involving keto (from ketone) and enol tautomers

Plasma particles, density 1.02–1.06 g/mL, consisting of approximately 26% proteins, 50% cholesterol, 21% phospholipids, and 4% triglycerides.

An electrophilic aromatic substitution reaction that involves the installation of a nitro group (NO2) on an aromatic ring.

A substance that does not ionize in water and consequently gives a nonconducting solution. (Section 4.1)

The conjugate base of phenol or a substituted phenol.

A material that can be formed into particular shapes by application of heat and pressure. (Section 12.8)

The structure of a protein resulting from the clustering of several individual protein chains into a final specific shape. (Section 24.7)

A carbohydrate that is oxidized upon treatment with Tollens’ reagent, Fehling’s reagent, or Benedict’s reagent.

An equilibrium constant related to the equilibrium between a solid salt and its ions in solution. It provides a quantitative measure of the solubility of a slightly soluble salt. (Section 17.4)

The highest energy point on a reaction coordinate diagram. The chemical structure at this point is commonly called an activated complex.

Rules for predicting the wavelength of maximum absorption for a compound with extended conjugation.