- 9.3.1: The standard heat of the reaction 2CO ! 2C O2 is H r 221:0 kJ. Use ...
- 9.3.2: H^ f is 28.64 kcal/mol for C3H8(l) and 24.82 kcal/mol for C3H8(g). ...
- 9.3.3: . Consider the reaction CH4 2O2 ! CO2 2H2Ov Write the formula for H...
Solutions for Chapter 9.3: FORMATION REACTIONS AND HEATS OF FORMATION
Full solutions for Elementary Principles of Chemical Processes | 4th Edition
A carbocation in which an allylic carbon bears the positive charge.
alpha (a) anomer
The cyclic hemiacetal of an aldose in which the hydroxyl group at the anomeric position is trans to the CH2OH
Compounds consisting of a single ring containing a fully conjugated p system. Benzene is annulene.
A form of magnetism in which unpaired electron spins on adjacent sites point in opposite directions and cancel each other’s effects. (Section 23.1)
atomic number (Z).
The number of protons in the nucleus of an atom. (2.3)
A polymer that is formed under conditions in which the monomers do not react directly with each other, but rather, each monomer is added to the growing chain, one at a time.
The most efficient arrangements for packing atoms, molecules, or ions in a crystal. (11.4)
A semiconducting material formed from two or more elements. (Section 12.7)
A cumulated diene is one in which two double bonds share an sp-hybridized carbon
An ArN2 1 or RN2 1 ion
A method for selectively cleaving and identifying the N-terminal amino acid of a polypeptide chain.
gas chromatograph – mass spectrometer
A device used for the analysis of a mixture that contains several compounds.
Heterolytic bond cleavage
Cleavage of a bond so that one fragment retains both electrons and the other retains none.
The tendency of nonpolar groups to cluster so as to shield them from contact with an aqueous environment.
A collection of Avogadro’s number 16.022 * 10232 of objects; for example, a mole of H2O is 6.022 * 1023 H2O molecules. (Section 3.4)
The breaking of a molecule into two or more neutral fragments as a result of absorption of light. (Section 18.2)
Refers to two hydrogens bonded to a carbon atom. When a different atom replaces one or the other, the carbon becomes a chiral center. The hydrogens of the CH2 group of ethanol, for example, are prochiral. Replacing one of them by deuterium gives (R)-1-deuteroethanol; replacing the other gives (S)-1-deuteroethanol
A mathematical description of an electron that incorporates its wavelike properties.
A vibrational molecular spectroscopy that is complementary to infrared (IR) spectroscopy in that infrared inactive vibrations are seen in Raman spectroscopy.
A recording in an NMR spectrum of a nuclear magnetic resonance