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Solutions for Chapter 17: Conjugated Pi Systems and Pericyclic Reactions

Organic Chemistry,  - Standalone Book | 2nd Edition | ISBN: 9781118452288 | Authors: David R. Klein

Full solutions for Organic Chemistry, - Standalone Book | 2nd Edition

ISBN: 9781118452288

Organic Chemistry,  - Standalone Book | 2nd Edition | ISBN: 9781118452288 | Authors: David R. Klein

Solutions for Chapter 17: Conjugated Pi Systems and Pericyclic Reactions

Solutions for Chapter 17
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Textbook: Organic Chemistry, - Standalone Book
Edition: 2
Author: David R. Klein
ISBN: 9781118452288

Since 79 problems in chapter 17: Conjugated Pi Systems and Pericyclic Reactions have been answered, more than 66273 students have viewed full step-by-step solutions from this chapter. Organic Chemistry, - Standalone Book was written by and is associated to the ISBN: 9781118452288. This expansive textbook survival guide covers the following chapters and their solutions. Chapter 17: Conjugated Pi Systems and Pericyclic Reactions includes 79 full step-by-step solutions. This textbook survival guide was created for the textbook: Organic Chemistry, - Standalone Book, edition: 2.

Key Chemistry Terms and definitions covered in this textbook
  • acid.

    A substance that yields hydrogen ions (H1) when dissolved in water. (2.7)

  • activated complex.

    The species temporarily formed by the reactant molecules as a result of the collision before they form the product. (13.4)

  • Allylic

    Next to a carbon-carbon double bond.

  • Carboxylic acid

    A compound containing a carboxyl, !COOH, group.

  • chromatogram

    In gas chromatography, a plot that identifies the retention time of each compound in the mixture.

  • diamagnetism

    The circulation of electron density in the presence of an external magnetic field, which produces a local (induced) magnetic field that opposes the external magnetic field.

  • diazonium salt

    An ionic compound that is formed upon treatment of a primary amine with NaNO2 and HCl.

  • diol

    A compound containing two hydroxyl groups (OH).

  • dipole-dipole interactions

    Theresulting net attraction between two dipoles.

  • Equivalent hydrogens

    Hydrogens that have the same chemical environment

  • Fingerprint region

    Vibrations in the region 1500 to 400 cm21 of an IR spectrum are complex and diffi cult to analyze but are characteristic for different molecules.

  • Gilman reagent

    A lithium dialkyl cuprate (R2CuLi).

  • Glycol

    A compound with hydroxyl (!OH) groups on adjacent carbons.

  • Homotopic groups

    Atoms or groups on an atom that give an achiral molecule when one of the groups is replaced by another group. The hydrogens of the CH2 group of propane, for example, are homotopic. Replacing either one of them with deuterium gives 2-deuteropropane, which is achiral. Homotopic groups have identical chemical shifts under all conditions

  • magnetic moment

    A magneticfield generated by a spinning proton.

  • main-group elements

    Elements in the s and p blocks of the periodic table. (Section 6.9)

  • phenyl group

    A C6H5 group.

  • Quantum mechanics

    The branch of science that studies the interaction of matter and radiation.

  • retro Diels-Alder reaction

    The reverse of a Diels-Alder reaction, achieved at high temperature. A cyclohexene derivative is converted into a diene and a dienophile.

  • Ring current

    An applied magnetic fi eld causes the p electrons of an aromatic ring to circulate, giving rise to the so-called ring current and an associated magnetic fi eld that opposes the applied fi eld in the middle of the ring but reinforces the applied fi eld on the outside of the ring.

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