- 17.17.1: For each of the following compounds, identify whether each CRC p sy...
- 17.17.2: Identify reagents necessary to convert cyclohexane into 1,3-cyclohe...
- 17.17.3: Rank the three C!C bonds of 1-butene in terms of bond length (from ...
- 17.17.4: Compare the following three isomeric dienes: (a) Which compound wil...
- 17.17.5: Identify the most stable compound:
- 17.17.6: Draw an energy diagram showing the relative energy levels of the MO...
- 17.17.7: Predict the products for each of the following reactions and propos...
- 17.17.8: Consider the following two dienes. When treated with HBr, one of th...
- 17.17.9: Propose the structure of a conjugated diene for which 1,2-addition ...
- 17.17.10: Predict the products for each of the following reactions, and in ea...
- 17.17.11: When 1,4-dimethylcyclohepta1,3-diene is treated with HBr at elevate...
- 17.17.12: When 1,3-cyclopentadiene is treated with HBr, the temperature does ...
- 17.17.13: What monomer should be used to make each of the following polymers:...
- 17.17.14: Predict the products for each of the following reactions: N N CN CN...
- 17.17.15: Predict the product(s) obtained when benzoquinone is treated with e...
- 17.17.16: Propose a mechanism for the following transformation: O O O O
- 17.17.17: Consider the following two isomers of 2,4-hexadiene. One isomer rea...
- 17.17.18: Rank the following dienes in terms of reactivity in DielsAlder reac...
- 17.17.19: Predict the products for each of the following reactions: (a) NC CN...
- 17.17.20: Consider the following [4+4] cycloaddition process. Would you expec...
- 17.17.21: Predict the major product(s) for each of the following thermal elec...
- 17.17.22: Predict the product(s) for each of the following reactions: Heat ? ...
- 17.17.23: Draw the structure of cis-3,4-diethylcyclobutene. (a) Conrotatory r...
- 17.17.24: Identify whether the product obtained from each of the following re...
- 17.17.25: For each of the following reactions, use brackets and two numbers t...
- 17.17.26: Consider the structure of cis-1,2-divinylcyclopropane: This compoun...
- 17.17.27: Predict the product for each of the following reactions: O (a) Heat...
- 17.17.28: Draw a plausible mechanism for the following transformation: Heat
- 17.17.29: Use Woodward-Fieser rules to estimate the expected lmax for each of...
- 17.17.30: Identify which of the following compounds is expected to have a lar...
- 17.17.31: For each of the following tasks, use the color wheel in Figure 17.3...
- 17.17.32: Draw the structure of each of the following compounds: (a) 1,4-Cycl...
- 17.17.33: Circle each compound that has a conjugated p system: O
- 17.17.34: For each of the following pairs of compounds determine whether the ...
- 17.17.35: Identify the structure of the conjugated diene that will react with...
- 17.17.36: Draw the major product expected when 1,3-butadiene is treated with ...
- 17.17.37: Draw the major product expected when 1,3-butadiene is treated with ...
- 17.17.38: Draw all four products obtained when 2-ethyl-3-methyl-1,3- cyclohex...
- 17.17.39: After performing the reaction from 17.38, the reaction flask is hea...
- 17.17.40: Each of the following compounds does not participate as a diene in ...
- 17.17.41: Rank the following dienophiles (from least reactive to most reactiv...
- 17.17.42: The absorbance spectrum of 1,3-butadiene displays an absorption in ...
- 17.17.43: Predict the products for each of the following Diels-Alder reaction...
- 17.17.44: Identify the reagents you would use to prepare each of the followin...
- 17.17.45: Starting with 1,3-butadiene as your only source of carbon atoms and...
- 17.17.46: The following triene reacts with excess maleic anhydride to produce...
- 17.17.47: Chlordane is a powerful insecticide that was used in the United Sta...
- 17.17.48: Cyclopentadiene reacts very rapidly in Diels-Alder reactions. In co...
- 17.17.49: Compound A (C7H10) exhibits a lmax of 230 nm in its UV absorption s...
- 17.17.50: Rank the following compounds in order of increasing lmax:
- 17.17.51: Which of the following compounds do you expect to have a longer lmax?
- 17.17.52: Predict the expected lmax of the following compound:
- 17.17.53: When 5-deutero-5-methyl-1,3-cyclopentadiene is warmed to room tempe...
- 17.17.54: Propose a plausible mechanism for the following transformation: D D...
- 17.17.55: Propose a method for achieving the following transformation:
- 17.17.56: Predict the product for each of the following electrocyclic reactio...
- 17.17.57: Predict which side of the following equilibrium is favored and expl...
- 17.17.58: When trans-3,4-dimethylcyclobutene is heated, conrotatory ring open...
- 17.17.59: Predict the product for each of the following reactions: O Heat (a)...
- 17.17.60: a-Terpinene is a pleasant-smelling compound present in the essentia...
- 17.17.61: Draw all possible conjugated dienes with molecular formula C6H10, t...
- 17.17.62: Treatment of 1,2-dibromocycloheptane with excess potassium tert-but...
- 17.17.63: In each of the following pairs of compounds identify the compound t...
- 17.17.64: Would you expect nitroethylene to be more or less reactive than eth...
- 17.17.65: Propose a plausible mechanism for the following transformation. (Hi...
- 17.17.66: When 2-methoxy-1,3-butadiene is treated with 3-buten-2- one, the re...
- 17.17.67: Propose a mechanism for the following transformation: H H H H Heat
- 17.17.68: Based on your answer to 17.67, propose a mechanism for the followin...
- 17.17.69: Compare the structures of 1,4-pentadiene and divinylamine: 1,4-Pent...
- 17.17.70: The poison gelsemoxonine can be isolated from the leaves of a plant...
- 17.17.71: Upon irradiation, some organic compounds undergo a reversible chang...
- 17.17.72: A hetero Diels-Alder reaction is a variation of the Diels-Alder rea...
- 17.17.73: During a recent investigation into the chemistry of oligofurans (po...
- 17.17.74: During the first total synthesis of chelidonine, a cytotoxic natura...
- 17.17.75: During studies directed toward the synthesis of atropurpuran, a dit...
- 17.17.76: When tricyclic cyclooctyne derivative A reacts with benzyl azide (C...
- 17.17.77: Endiandric acids are a class of natural products isolated from the ...
- 17.17.78: Roquefortine C belongs to a family of natural products first isolat...
- 17.17.79: As shown below, compound 1 can be transformed to compound 2, which ...
Solutions for Chapter 17: Conjugated Pi Systems and Pericyclic Reactions
Full solutions for Organic Chemistry, - Standalone Book | 2nd Edition
ISBN: 9781118452288
Since 79 problems in chapter 17: Conjugated Pi Systems and Pericyclic Reactions have been answered, more than 233413 students have viewed full step-by-step solutions from this chapter. Organic Chemistry, - Standalone Book was written by and is associated to the ISBN: 9781118452288. This expansive textbook survival guide covers the following chapters and their solutions. Chapter 17: Conjugated Pi Systems and Pericyclic Reactions includes 79 full step-by-step solutions. This textbook survival guide was created for the textbook: Organic Chemistry, - Standalone Book, edition: 2.
-
activate
For a substituted aromatic ring, the effect of an electron-donating substituent that increases the rate of electrophilic aromatic substitution.
-
alkyl halide
An organic compound containing at least one halogen.
-
base-dissociation constant (Kb)
An equilibrium constant that expresses the extent to which a base reacts with solvent water, accepting a proton and forming OH-1aq2. (Section 16.7)
-
Celsius scale
A temperature scale on which water freezes at 0° and boils at 100° at sea level. (Section 1.4)
-
doublet
In NMR spectroscopy, a signal that is comprised of two peaks.
-
electrochemistry
The branch of chemistry that deals with the relationships between electricity and chemical reactions. (Chapter 20: Introduction)
-
Histone
A protein, particularly rich in the basic amino acids lysine and arginine, that is found associated with DNA molecules
-
Hyperconjugation
Interaction of electrons in a s-bonding orbital with the vacant 2p orbital of an adjacent positively charged carbon.
-
insulators
Materials that do not conduct electricity. (Section 12.7)
-
microstate
The state of a system at a particular instant; one of many possible energetically equivalent ways to arrange the components of a system to achieve a particular state. (Section 19.3)
-
Monomer
From the Greek, mono 1 meros, meaning single part. The simplest nonredundant unit from which a polymer is synthesized.
-
N-Terminal amino acid
The amino acid at the end of a polypeptide chain having the free !NH2 group
-
node
In atomic and molecular orbitals, a location where the value of y is zero.
-
Node
A point in space where the value of a wave function is zero
-
nonmetallic elements (nonmetals)
Elements in the upper right corner of the periodic table; nonmetals differ from metals in their physical and chemical properties. (Section 2.5)
-
nuclear model
Model of the atom with a nucleus containing protons and neutrons and with electrons in the space outside the nucleus. (Section 2.2)
-
oxidation number (oxidation state)
A positive or negative whole number assigned to an element in a molecule or ion on the basis of a set of formal rules; to some degree it reflects the positive or negative character of that atom. (Section 4.4)
-
sulfonation
An electrophilic aromatic substitution reaction in which an SO3H group is installed on an aromatic ring.
-
Tollens’ reagent
A solution prepared by dissolving Ag2O in aqueous ammonia; used for selective oxidation of an aldehyde to a carboxylic acid.
-
Valence electrons
Electrons in the valence (outermost) shell of an atom.