- 20.20.1: Assign a systematic (IUPAC) name to each of the following compounds...
- 20.20.2: Draw the structure of each of the following compounds: (a) (S)-3,3-...
- 20.20.3: Provide a systematic (IUPAC) name for the compound below. Be carefu...
- 20.20.4: Compounds with two ketone groups are named as alkane diones; for ex...
- 20.20.5: Identify the reagents necessary to achieve each of the following tr...
- 20.20.6: Draw a mechanism for each of the following reactions: 1) EtMgBr 2) ...
- 20.20.7: For most ketones, hydrate formation is unfavorable, because the equ...
- 20.20.8: Draw a plausible mechanism for each of the following transformation...
- 20.20.9: Draw a plausible mechanism for each of the following reactions: (b)...
- 20.20.10: Predict the product of each of the following reactions: [H2SO4] exc...
- 20.20.11: Propose an efficient synthesis for each of the following transforma...
- 20.20.12: Predict the product(s) for each reaction below: (a) (c) OO H3O+ H3O...
- 20.20.13: Draw a plausible mechanism for the following transformation: OH O O...
- 20.20.14: Compound A has molecular formula C8H14O2. Upon treatment with catal...
- 20.20.15: Draw a plausible mechanism for each of the following transformation...
- 20.20.16: Predict the major product for each of the following reactions: [H+]...
- 20.20.17: Predict the major product for each of the following intramolecular ...
- 20.20.18: Identify the reactants that you would use to make each of the follo...
- 20.20.19: Predict the product of each of the following reactions: O HONH2 [H+...
- 20.20.20: Identify the reactants that you would use to make each of the follo...
- 20.20.21: Draw a plausible mechanism for each of the following reactions: O N...
- 20.20.22: Predict the major product for each of the following reactions: O (a...
- 20.20.23: Predict the major product for each of the following intramolecular ...
- 20.20.24: Identify the reactants that you would use to make each of the follo...
- 20.20.25: Predict the product of the following two-step procedure and draw a ...
- 20.20.26: Draw the products that are expected for each of the following react...
- 20.20.27: Draw the products that are expected for each of the following react...
- 20.20.28: As shown above, methenamine is hydrolyzed in aqueous acid to produc...
- 20.20.29: Predict the major product for each of the following: O 2) Raney Ni ...
- 20.20.30: Draw the structure of the cyclic compound that is produced when ace...
- 20.20.31: Predict the major product for each of the following reactions: ? 1)...
- 20.20.32: When 2 moles of benzaldehyde are treated with sodium hydroxide, a r...
- 20.20.33: Predict the major product for each of the following: (a) O 1) EtMgB...
- 20.20.34: Identify the reagents necessary to accomplish each of the transform...
- 20.20.35: Predict the major product for each of the following reaction sequen...
- 20.20.36: Identify the reagents necessary to accomplish each of the transform...
- 20.20.37: Identify the reagents necessary to prepare each of the following co...
- 20.20.38: Consider the structure of beta-carotene, mentioned earlier in this ...
- 20.20.39: Identify the reagents necessary to accomplish each of the transform...
- 20.20.40: Predict the major product of each reaction below: O RCO3H (a) ? RCO...
- 20.20.41: Propose an efficient synthesis for each of the following transforma...
- 20.20.42: Using any compounds of your choosing, identify a method for prepari...
- 20.20.43: Compound A has molecular formula C10H10O and exhibits a strong sign...
- 20.20.44: Provide a systematic (IUPAC) name for each of the following compoun...
- 20.20.45: Draw the structure for each compound below: (a) Propanedial (b) 4-P...
- 20.20.46: Draw all constitutionally isomeric aldehydes with molecular formula...
- 20.20.47: Draw all constitutionally isomeric aldehydes with molecular formula...
- 20.20.48: Draw all constitutionally isomeric ketones with molecular formula C...
- 20.20.49: Explain why the IUPAC name of a compound is unlikely to have the su...
- 20.20.50: For each pair of the following compounds, identify which compound w...
- 20.20.51: Draw the products of each Wittig reaction below. If two stereoisome...
- 20.20.52: Draw the structure of the alkyl halide needed to prepare each of th...
- 20.20.53: Show how a Wittig reaction can be used to prepare each of the follo...
- 20.20.54: Choose a Grignard reagent and a ketone that can be used to produce ...
- 20.20.55: You are working in a laboratory, and you are given the task of conv...
- 20.20.56: Predict the major product(s) from the treatment of acetone with the...
- 20.20.57: Propose a plausible mechanism for the following transformation: [H+...
- 20.20.58: Devise an efficient synthesis for the following transformation (rec...
- 20.20.59: Treatment of catechol with formaldehyde in the presence of an acid ...
- 20.20.60: Predict the major product(s) for each reaction below. (c) O (C6H5) ...
- 20.20.61: Starting with cyclopentanone and using any other reagents of your c...
- 20.20.62: Glutaraldehyde is a germicidal agent that is sometimes used to ster...
- 20.20.63: Predict the major product(s) obtained when each of the following co...
- 20.20.64: Identify all of the products formed when the compound below is trea...
- 20.20.65: Draw a plausible mechanism for each of the following transformation...
- 20.20.66: Predict the major product(s) for each of the following reactions: O...
- 20.20.67: Identify the starting materials needed to make each of the followin...
- 20.20.68: Using ethanol as your only source of carbon atoms, design a synthes...
- 20.20.69: Propose an efficient synthesis for each of the following transforma...
- 20.20.70: The compound below is believed to be a wasp pheromone. Draw the maj...
- 20.20.71: Propose an efficient synthesis for each of the following transforma...
- 20.20.72: Draw a plausible mechanism for the following transformation: NH2 NH...
- 20.20.73: When cyclohexanone is treated with H2O, an equilibrium is establish...
- 20.20.74: Consider the three constitutional isomers of dioxane (C4H8O2): O O ...
- 20.20.75: Propose an efficient synthesis for each of the following transforma...
- 20.20.76: Compound A has molecular formula C7H14O and reacts with sodium boro...
- 20.20.77: Using the information provided below, deduce the structures of comp...
- 20.20.78: Identify the structures of compounds A to D below and then identify...
- 20.20.79: Identify the structures of compounds A to E below: Br2 FeBr3 A Mg B...
- 20.20.80: An aldehyde with molecular formula C4H6O exhibits an IR signal at 1...
- 20.20.81: A compound with molecular formula C9H10O exhibits a strong signal a...
- 20.20.82: A compound with molecular formula C13H10O produces a strong signal ...
- 20.20.83: A ketone with molecular formula C9H18O exhibits only one signal in ...
- 20.20.84: Draw a plausible mechanism for each of the following transformation...
- 20.20.85: Under acid-catalyzed conditions, formaldehyde polymerizes to produc...
- 20.20.86: The following transformation was employed during synthetic studies ...
- 20.20.87: Propose an efficient synthesis for the conversion of the following ...
- 20.20.88: The reaction of cyclohexanone with the given optically pure aminoes...
- 20.20.89: Which of the following is the correct sequence of reactions needed ...
- 20.20.90: Furo[2,3-b]indoles are compounds whose structural features are pres...
- 20.20.91: In a Bamford-Stevens-Shapiro reaction, a sulfonylhydrazone (1) unde...
- 20.20.92: A convenient method for achieving the transformation below involves...
- 20.20.93: During a recent synthesis of hispidospermidin, a fungal isolate and...
- 20.20.94: During a recent total synthesis of kibdelone C, a cytotoxic natural...
- 20.20.95: Treatment of the following ketone with LAH affords two products, A ...
Solutions for Chapter 20: Aldehydes and Ketones
Full solutions for Organic Chemistry, - Standalone Book | 2nd Edition
ISBN: 9781118452288
Chapter 20: Aldehydes and Ketones includes 95 full step-by-step solutions. Since 95 problems in chapter 20: Aldehydes and Ketones have been answered, more than 233938 students have viewed full step-by-step solutions from this chapter. Organic Chemistry, - Standalone Book was written by and is associated to the ISBN: 9781118452288. This textbook survival guide was created for the textbook: Organic Chemistry, - Standalone Book, edition: 2. This expansive textbook survival guide covers the following chapters and their solutions.
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Aprotic acid
An acid that is not a proton donor; an acid that is an electron pair acceptor in a Lewis acid-base reaction.
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azo dyes
A class of colored compounds that are formed via azo coupling.
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battery
A self-contained electrochemical power source that contains one or more voltaic cells. (Section 20.7)
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bond length.
The distance between the nuclei of two bonded atoms in a molecule. (9.4)
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calcination
The heating of an ore to bring about its decomposition and the elimination of a volatile product. For example, a carbonate ore might be calcined to drive off CO2. (Section 23.2)
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dextrorotatory
A compound that rotates plane-polarized light in a clockwise direction (+).
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Elastomer
A material that, when stretched or otherwise distorted, returns to its original shape when the distorting force is released.
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elementary reaction
A process in a chemical reaction that occurs in a single step. An overall chemical reaction consists of one or more elementary reactions or steps. (Section 14.6)
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Haber process
The catalyst system and conditions of temperature and pressure developed by Fritz Haber and coworkers for the formation of NH3 from H2 and N2. (Section 15.2)
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haloalkane
An organic compound containing at least one halogen.
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Hyperconjugation
Interaction of electrons in a s-bonding orbital with the vacant 2p orbital of an adjacent positively charged carbon.
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internal alkyne
A compound with the structure R!C#C!R, where each R group is not a hydrogen atom.
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lanthanide contraction
The gradual decrease in atomic and ionic radii with increasing atomic number among the lanthanide elements, atomic numbers 57 through 70. The decrease arises because of a gradual increase in effective nuclear charge through the lanthanide series. (Section 23.1)
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law of constant composition
A law that states that the elemental composition of a pure compound is always the same, regardless of its source; also called the law of definite proportions. (Section 1.2)
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N-glycoside
The product obtained when a monosaccharide is treated with an amine in the presence of an acid catalyst.
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polarimeter
A device that measures the rotation of plane-polarized light caused by optically active compounds.
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Protic acid
An acid that is a proton donor in an acidbase reaction.
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R (Section 3.3)
From the Latin, rectus, straight, correct; used in the R,S convention to show that the order of priority of groups on a chiral center is clockwise.
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spectator ions
Ions that go through a reaction unchanged and that appear on both sides of the complete ionic equation. (Section 4.2)
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Wavelength (l)
The distance between consecutive peaks on a wave