Solutions for Chapter 14: Chemistry: The Central Science 12th Edition

Chemistry: The Central Science | 12th Edition | ISBN: 9780321696724 | Authors: Theodore E. Brown

Full solutions for Chemistry: The Central Science | 12th Edition

ISBN: 9780321696724

Chemistry: The Central Science | 12th Edition | ISBN: 9780321696724 | Authors: Theodore E. Brown

Solutions for Chapter 14

Solutions for Chapter 14
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Textbook: Chemistry: The Central Science
Edition: 12
Author: Theodore E. Brown
ISBN: 9780321696724

Chemistry: The Central Science was written by Sieva Kozinsky and is associated to the ISBN: 9780321696724. This textbook survival guide was created for the textbook: Chemistry: The Central Science, edition: 12. This expansive textbook survival guide covers the following chapters and their solutions. Since 138 problems in chapter 14 have been answered, more than 58209 students have viewed full step-by-step solutions from this chapter. Chapter 14 includes 138 full step-by-step solutions.

Key Chemistry Terms and definitions covered in this textbook
  • Brønsted-Lowry base

    A compound that can serve as a proton acceptor.

  • C-Terminal amino acid

    The amino acid at the end of a polypeptide chain having the free !COOH group.

  • coordination-sphere isomers

    Structural isomers of coordination compounds in which the ligands within the coordination sphere differ. (Section 23.4)

  • epimer

    Diastereomers that differ from each other in the configuration of only one chirality center.

  • exothermic

    Any process with a negative DH (the system gives energy to the surroundings).

  • homolitic bond cleavage

    Bond breaking that results in the formation of unchanged species called radicals.

  • hydroperoxide

    A compound with the structure R!O!O!H.

  • ideal solution

    A solution that obeys Raoult’s law. (Section 13.5)

  • immiscible liquids

    Liquids that do not dissolve in one another to a significant extent. (Section 13.3)

  • Lewis dot structure

    The symbol of an element surrounded by a number of dots equal to the number of electrons in the valence shell of the atom

  • Low-resolution mass spectrometry

    Instrumentation that is capable of separating only ions that differ in mass by 1 or more amu.

  • N-bromosuccinimide

    A reagent used for allylic bromination to avoid a competing reaction in which bromine adds across the p bond.

  • nitrogen rule

    In mass spectrometry, an odd molecular weight indicates an odd number of nitrogen atoms in the compound, while an even molecular weight indicates either an even number of nitrogen atoms or the absence of nitrogen.

  • Polyester

    A polymer in which each monomer unit is joined to the next by an ester bond, as, for example, poly(ethylene terephthalate).

  • precision

    The closeness of agreement among several measurements of the same quantity; the reproducibility of a measurement. (Section 1.5)

  • rate constant

    A constant of proportionality between the reaction rate and the concentrations of reactants that appear in the rate law. (Section 14.3)

  • reductive amination

    The conversion of a ketone or aldehyde into an imine under conditions in which the imine is reduced as soon as it is formed, giving an amine.

  • Synstereoselective

    The addition of atoms or groups of atoms to the same face of a carbon-carbon double bond.

  • tosylate

    An excellent leaving group (OTs). transition state (Sect. 6.6): A state through which a reaction passes. On an energy diagram, a transition state corresponds with a local maximum.

  • Woodward-Fieser rules

    Rules for predicting the wavelength of maximum absorption for a compound with extended conjugation.

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