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Solutions for Chapter 14: D e l o c a l i z e d P i S y s t e m s

Organic Chemistry, | 6th Edition | ISBN: 9781429204941 | Authors: K. Peter C. Vollhardt Neil E. Schore

Full solutions for Organic Chemistry, | 6th Edition

ISBN: 9781429204941

Organic Chemistry, | 6th Edition | ISBN: 9781429204941 | Authors: K. Peter C. Vollhardt Neil E. Schore

Solutions for Chapter 14: D e l o c a l i z e d P i S y s t e m s

Solutions for Chapter 14
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Textbook: Organic Chemistry,
Edition: 6
Author: K. Peter C. Vollhardt Neil E. Schore
ISBN: 9781429204941

This expansive textbook survival guide covers the following chapters and their solutions. Organic Chemistry, was written by and is associated to the ISBN: 9781429204941. Since 50 problems in chapter 14: D e l o c a l i z e d P i S y s t e m s have been answered, more than 14433 students have viewed full step-by-step solutions from this chapter. This textbook survival guide was created for the textbook: Organic Chemistry,, edition: 6. Chapter 14: D e l o c a l i z e d P i S y s t e m s includes 50 full step-by-step solutions.

Key Chemistry Terms and definitions covered in this textbook
  • Aceto group

    A CH3CO! group; also called an acetyl group

  • Aprotic solvent

    A solvent that cannot serve as a hydrogen-bond donor; nowhere in the molecule is there a hydrogen bonded to an atom of high electronegativity. Common aprotic solvents are dichloromethane, diethyl ether, and dimethyl sulfoxide

  • barometer

    An instrument that measures atmospheric pressure. (5.2)

  • blocking group

    A group that can be readily installed and uninstalled. Used for regiochemical control during synthesis.

  • cellulose

    A polysaccharide of glucose; it is the major structural element in plant matter. (Section 24.8)

  • combination reaction.

    A reaction in which two or more substances combine to form a single product. (4.4)

  • condensation reaction

    A chemical reaction in which a small molecule (such as a molecule of water) is split out from between two reacting molecules. (Sections 12.6 and 22.8)

  • eicosanoids

    A class of lipids which includes leukotrienes, prostaglandins, thromboxanes, and prostacyclins.

  • electromagnetic spectrum

    Therange of all frequencies of electromagnetic radiation,which is arbitrarily divided into severalregions, most commonly by wavelength.

  • geometric isomerism

    A form of isomerism in which compounds with the same type and number of atoms and the same chemical bonds have different spatial arrangements of these atoms and bonds. (Sections 23.4 and 24.4)

  • Hammond postulate

    In an exothermic process the transition state is closer in energy to the reactants than to the products, and therefore the structure of the transition state more closely resembles the reactants. In contrast, the transition state in an endothermic process is closer in energy to the products, and therefore the transition state more closely resembles the products.

  • Henderson–Hasselbalch equation

    The relationship among the pH, pKa, and the concentrations of acid and conjugate base in an aqueous solution: pH = pKa + log 3base4 3acid4. (Section 17.2)

  • hydrazone

    A compound with the structure R2CRN!NH2.

  • lattice energy

    The energy required to separate completely the ions in an ionic solid. (Section 8.2)

  • loss of a leaving group

    One of the four arrow-pushing patterns for ionic reactions.

  • nucleon

    A particle found in the nucleus of an atom. (Section 21.1)

  • nucleotides

    The product formed when a nucleoside is coupled to a phosphate group

  • R

    A term used to designate the configuration of a chirality center, determined in the following way: Each of the four groups is assigned a priority, and the molecule is then rotated (if necessary) so that the #4 group is directed behind the page (on a dash). A clockwise sequence for 1-2-3 is designated as R.

  • solvolysis

    A substitution reaction in which the solvent functions as the nucleophile.

  • unimolecular

    For mechanisms, astep that involves only one chemical entity.

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