- 2.2.1: a. Which compounds are BrnstedLowry acids: HBr, NH3, CCl4? b. Which...
- 2.2.2: a. Draw the conjugate acid of each base: NH3, Cl , (CH3)2C O. b. Dr...
- 2.2.3: The presence of a bond also makes a compound a base. With this in m...
- 2.2.4: Label the acid and base, and the conjugate acid and base in the fol...
- 2.2.5: Draw the products of each proton transfer reaction. a. CCl3CO2H + O...
- 2.2.6: Draw the products formed from the acidbase reaction of HCl with eac...
- 2.2.7: Which compound in each pair is the stronger acid? a. CH3CH2CH3 or C...
- 2.2.8: Use a calculator when necessary to answer the following questions. ...
- 2.2.9: Rank the conjugate bases of each group of acids in order of increas...
- 2.2.11: Estimate the pKa of each of the indicated bonds. a. H N H b. O H c....
- 2.2.12: Draw the products of each reaction and determine the direction of e...
- 2.2.13: Answer the following questions by referring to Table 2.1: a. Which ...
- 2.2.14: Using the data in Appendix A, determine which of the following base...
- 2.2.15: Without reference to a pKa table, decide which compound in each pai...
- 2.2.16: Which compound in each pair of isomers is the stronger acid? a. CH3...
- 2.2.17: Which hydrogen in each molecule is most acidic? a. CH3CH2CH2CH2OH b...
- 2.2.18: Which hydrogen in pseudoephedrine, the nasal decongestant in the co...
- 2.2.19: Which compound in each pair is the stronger acid? a. ClCH2COOH or F...
- 2.2.21: The C H bond in acetone, (CH3)2C O, has a pKa of 19.2. Draw two res...
- 2.2.22: Acetonitrile (CH3CN) has a pKa of 25, making it more acidic than ma...
- 2.2.23: For each pair of compounds: [1] Which indicated H is more acidic? [...
- 2.2.24: Rank the compounds in each group in order of increasing acidity. a....
- 2.2.25: Which proton in each of the following drugs is most acidic? THC is ...
- 2.2.26: Draw the products formed when 2-propanol [(CH3)2CHOH], the main ing...
- 2.2.27: Compounds like amphetamine that contain nitrogen atoms are protonat...
- 2.2.28: Which compounds are Lewis bases? a. NH3 b. CH3CH2CH3 c. H d. H C C H
- 2.2.29: Which compounds are Lewis acids? a. BBr3 b. CH3CH2OH c. (CH3)3C+ d. Br
- 2.2.31: Draw the products of each reaction, and label the nucleophile and e...
- 2.2.32: Draw the product formed when (CH3CH2)3N:, a Lewis base, reacts with...
- 2.2.33: Label the Lewis acid and base. Use curved arrow notation to show th...
- 2.2.34: What is the conjugate acid of each base? a. H2O b. NH2 c. HCO3 d. C...
- 2.2.35: What is the conjugate base of each acid? a. HCN b. HCO3 c. (CH3)2 +...
- 2.2.36: Draw the products formed from the acidbase reaction of H2SO4 with e...
- 2.2.37: Draw the products formed from the acidbase reaction of KOH with eac...
- 2.2.38: Draw the products of each proton transfer reaction. Label the acid ...
- 2.2.39: Draw the products of each acidbase reaction. a. COOH + NH3 d. CH3CH...
- 2.2.41: Draw the products of each acidbase reaction. a. H CH3 CH3O COOH NaO...
- 2.2.42: Fenfluramine and phentermine are two components of fenphen, an appe...
- 2.2.43: What is Ka for each compound? Use a calculator when necessary. a. H...
- 2.2.44: What is the pKa for each compound? Use a calculator when necessary....
- 2.2.45: Which bases in Table 2.1 are strong enough to deprotonate each comp...
- 2.2.46: Which of the following bases are strong enough to deprotonate CH3CH...
- 2.2.47: Which compounds can be deprotonated by OH, so that equilibrium favo...
- 2.2.48: Draw the products of each reaction. Use the pKa table in Appendix A...
- 2.2.49: Rank the following compounds in order of increasing acidity. a. NH3...
- 2.2.51: The pKas of the two ammonium cations drawn below are 8.33 and 11.1....
- 2.2.52: Explain why the pKa of propiolic acid (HC CCO2H, pKa = 1.8) is sign...
- 2.2.53: The pKa of three different C H bonds is given below. CH3CH2CH2 H CH...
- 2.2.54: a. What is the conjugate acid of A? b. What is the conjugate base o...
- 2.2.55: Many drugs are BrnstedLowry acids or bases. a. What is the most aci...
- 2.2.56: The pKa of nitromethane (CH3NO2) is 10, making its C H bond more ac...
- 2.2.57: Dimethyl ether (CH3OCH3) and ethanol (CH3CH2OH) are isomers, but CH...
- 2.2.58: Atenolol is a (beta) blocker, a drug used to treat high blood press...
- 2.2.59: Ethyl butanoate, CH3CH2CH2CO2CH2CH3, is one of the many organic com...
- 2.2.61: Label the three most acidic hydrogen atoms in lactic acid, CH3CH(OH...
- 2.2.62: Classify each compound as a Lewis base, a BrnstedLowry base, both, ...
- 2.2.63: Classify each species as a Lewis acid, a BrnstedLowry acid, both, o...
- 2.2.64: Label the Lewis acid and Lewis base in each reaction. Use curved ar...
- 2.2.65: Draw the products of each Lewis acidbase reaction. Label the electr...
- 2.2.66: Draw the product formed when the Lewis acid (CH3CH2)3C+ reacts with...
- 2.2.67: Classify each reaction as either a proton transfer reaction, or a r...
- 2.2.68: Hydroxide ( OH) can react as a BrnstedLowry base (and remove a prot...
- 2.2.69: Answer the following questions about esmolol, a drug used to treat ...
- 2.2.71: Two pKa values are reported for malonic acid, a compound with two C...
- 2.2.72: Amino acids such as glycine are the building blocks of large molecu...
- 2.2.73: Write a stepwise reaction sequence using proton transfer reactions ...
- 2.2.74: Which H atom in vitamin C (ascorbic acid) is most acidic? O O HO OH...
Solutions for Chapter 2: Acids and Bases
Full solutions for Organic Chemistry | 3rd Edition
ISBN: 9780077354725
This textbook survival guide was created for the textbook: Organic Chemistry, edition: 3. This expansive textbook survival guide covers the following chapters and their solutions. Chapter 2: Acids and Bases includes 67 full step-by-step solutions. Organic Chemistry was written by and is associated to the ISBN: 9780077354725. Since 67 problems in chapter 2: Acids and Bases have been answered, more than 220168 students have viewed full step-by-step solutions from this chapter.
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a-Carbon
A carbon atom adjacent to a carbonyl group
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aldose
A carbohydrate that contains an aldehyde group.
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benzyne
A high-energy intermediate formed during the elimination-addition reaction that occurs between chlorobenzene and either NaOH (at high temperature) or NaNH2.
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cathode
An electrode at which reduction occurs. (Section 20.3)
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electrolytic cell
A device in which a nonspontaneous oxidation–reduction reaction is caused to occur by passage of current under a sufficient external electrical potential. (Section 20.9)
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enolate
The resonance-stabilized conjugate base of a ketone, aldehyde, or ester.
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Fishhook arrow
A barbed curved arrow used to show the change in position of a single electron.
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geometric isomerism
A form of isomerism in which compounds with the same type and number of atoms and the same chemical bonds have different spatial arrangements of these atoms and bonds. (Sections 23.4 and 24.4)
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Heat of combustion (DH0 )
Standard heat of combustion is the heat released when one mole of a substance in its standard state (gas, liquid, solid) is oxidized completely to carbon dioxide and water.
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heat of sublimation
The enthalpy change, ?H, for vaporization of a solid. (Section 11.4)
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hole
A vacancy in the valence band of a semiconductor, created by doping. (Section 12.7)
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hydrophilic
Water attracting. The term is often used to describe a type of colloid. (Section 13.6)
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molecular solids
Solids that are composed of molecules. (Sections 12.1 and 12.6)
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Monomer
From the Greek, mono 1 meros, meaning single part. The simplest nonredundant unit from which a polymer is synthesized.
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Node
A point in space where the value of a wave function is zero
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Organic synthesis
A series of reactions by which a set of organic starting materials is converted to a more complicated structure.
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Reaction coordinate diagram
A graph showing the energy changes that occur during a chemical reaction; energy is plotted on the vertical axis and reaction progress is plotted on the horizontal axis.
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sp3 Hybrid orbital
A hybrid atomic orbital formed by the combination of one s atomic orbital and three 2p atomic orbitals.
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symmetric stretching
In IR spectroscopy, when two bonds are stretching in phase with each other.
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Z
For alkenes, a stereodescriptor that indicates that the two priority groups are on the same side of the p bond.