- 12.12.1: Classify each reaction as oxidation, reduction, or neither. a. O c....
- 12.12.2: What alkane is formed when each alkene is treated with H2 and a Pd ...
- 12.12.3: Draw all alkenes that react with one equivalent of H2 in the presen...
- 12.12.4: Which alkene in each pair has the larger heat of hydrogenation? a. ...
- 12.12.5: Explain why heats of hydrogenation cannot be used to determine the ...
- 12.12.6: What product is formed when limonene is treated with one equivalent...
- 12.12.7: Given that syn addition of H2 occurs from both sides of a trigonal ...
- 12.12.8: Complete the missing information for compounds A, B, and C, each su...
- 12.12.9: Draw the products formed when triacylglycerol A is treated with eac...
- 12.12.11: What is the structure of cis-jasmone, a natural product isolated fr...
- 12.12.12: Draw the organic products formed in each hydrogenation. a. CH2 CHCH...
- 12.12.13: What product is formed when CH3OCH2CH2C CCH2CH(CH3)2 is treated wit...
- 12.12.14: Deuterium is introduced into a molecule by using reducing agents th...
- 12.12.15: A chiral alkyne A with molecular formula C6H10 is reduced with H2 a...
- 12.12.16: Draw the products of each reaction. a. Cl [1] LiAlH4 [2] H2O b. [1]...
- 12.12.17: What epoxide is formed when each alkene is treated with mCPBA? a. (...
- 12.12.18: Draw all stereoisomers formed when each alkene is treated with mCPB...
- 12.12.19: Draw the products formed when both cis- and trans-2-butene are trea...
- 12.12.21: Draw the products formed when each alkene is treated with O3 follow...
- 12.12.22: What alkene yields each set of oxidative cleavage products? a. (CH3...
- 12.12.23: Draw the products formed when each diene is treated with O3 followe...
- 12.12.24: Draw the products formed when each alkyne is treated with O3 follow...
- 12.12.25: What alkyne (or diyne) yields each set of oxidative cleavage produc...
- 12.12.26: Draw the organic products in each of the following reactions. a. OH...
- 12.12.27: What carbonyl compound is formed when each alcohol is treated with ...
- 12.12.28: Sodium hypochlorite (NaOCl, the oxidant in household bleach) in aqu...
- 12.12.29: Ethylene glycol, HOCH2CH2OH, is an extremely toxic diol because its...
- 12.12.31: Explain why only one C C of geraniol is epoxidized with the Sharple...
- 12.12.32: Label each reaction as oxidation, reduction, or neither. a. C CH CH...
- 12.12.33: Draw the organic products formed when each alkene is treated with H...
- 12.12.34: Match each alkene to its heat of hydrogenation. Alkenes: 3-methyl-1...
- 12.12.35: How many rings and bonds are contained in compounds AC? Draw one po...
- 12.12.36: For alkenes A, B, and C: (a) Rank A, B, and C in order of increasin...
- 12.12.37: A chiral compound X having the molecular formula C6H12 is converted...
- 12.12.38: Stearidonic acid (C18H28O2) is an unsaturated fatty acid obtained f...
- 12.12.39: Draw the organic products formed when cyclopentene is treated with ...
- 12.12.41: Draw the organic products formed when allylic alcohol A is treated ...
- 12.12.42: Draw the products formed when allylic alcohol B is treated with eac...
- 12.12.43: Draw the organic products formed in each reaction. a. PCC OH b. CH3...
- 12.12.44: Draw the organic products formed in each reaction. a. OH [1] SOCI2,...
- 12.12.45: Identify the reagents needed to carry out each transformation. O (b...
- 12.12.46: What alkene is needed to synthesize each 1,2-diol using [1] OsO4 fo...
- 12.12.47: Draw a stepwise mechanism for the reduction of epoxide A to alcohol...
- 12.12.48: Draw the products formed after Steps [1] and [2] in the following t...
- 12.12.49: Draw the products formed in each oxidative cleavage. a. (CH3CH2)2C ...
- 12.12.51: Identify the starting material in each reaction. a. O O H [1] O3 [2...
- 12.12.52: What alkyne gives each set of products after treatment with O3 foll...
- 12.12.53: Draw the products formed when each naturally occurring compound is ...
- 12.12.54: Identify compounds A, B, and C. a. Compound A has molecular formula...
- 12.12.55: Oximene and myrcene, two hydrocarbons isolated from alfalfa that ha...
- 12.12.56: An achiral hydrocarbon A of molecular formula C7H12 reacts with two...
- 12.12.57: An unknown compound A of molecular formula C10H18O reacts with H2SO...
- 12.12.58: DHA is a fatty acid derived from fi sh oil and an abundant fatty ac...
- 12.12.59: One compound that contributes to the seashore smell at beaches in H...
- 12.12.61: Epoxidation of the following allylic alcohol using the Sharpless re...
- 12.12.62: What allylic alcohol and DET isomer are needed to make each chiral ...
- 12.12.63: Devise a synthesis of each hydrocarbon from acetylene, and any othe...
- 12.12.64: Devise a synthesis of muscalure, the sex pheromone of the common ho...
- 12.12.65: It is sometimes necessary to isomerize a cis alkene to a trans alke...
- 12.12.66: Devise a synthesis of each compound from acetylene and any other re...
- 12.12.67: Devise a synthesis of each compound from styrene (C6H5CH CH2). You ...
- 12.12.68: Devise a synthesis of (2E)-2-hexene from 1-pentene and any needed o...
- 12.12.69: Devise a synthesis of each compound from the indicated starting mat...
- 12.12.71: Devise a synthesis of each compound from ethynylcyclohexane. You ma...
- 12.12.72: Devise a synthesis of (3R,4S)-3,4-dichlorohexane from acetylene and...
- 12.12.73: Devise a synthesis of each compound from CH3CH2OH as the only organ...
- 12.12.74: The Birch reduction is a dissolving metal reaction that converts su...
- 12.12.75: In the Cr6+ oxidation of cyclohexanols, it is generally true that s...
- 12.12.76: Draw a stepwise mechanism for the following reaction. O O O OH OSiR...
- 12.12.77: Although reagents can always add to an alkene from either side, som...
Solutions for Chapter 12: Oxidation and Reduction
Full solutions for Organic Chemistry | 3rd Edition
ISBN: 9780077354725
Solutions for Chapter 12
27
5
This textbook survival guide was created for the textbook: Organic Chemistry, edition: 3. Chapter 12: Oxidation and Reduction includes 70 full step-by-step solutions. Since 70 problems in chapter 12: Oxidation and Reduction have been answered, more than 65894 students have viewed full step-by-step solutions from this chapter. Organic Chemistry was written by and is associated to the ISBN: 9780077354725. This expansive textbook survival guide covers the following chapters and their solutions.
Key Chemistry Terms and definitions covered in this textbook
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acid.
A substance that yields hydrogen ions (H1) when dissolved in water. (2.7)
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acyl peroxide
A peroxide for which each oxygen atom is connected to an acyl group. Acyl peroxides are often used as radical initiators, because the O!O bond is especially weak.
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addition polymers
Polymers that are formed via cationic addition, anionic addition, or free-radical addition.
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alkaline earth metals.
The Group 2A elements (Be, Mg, Ca, Sr, Ba, and Ra). (2.4)
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Anabolic steroid
A steroid hormone, such as testosterone, that promotes tissue and muscle growth and development
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Aromatic compound
A term used initially to classify benzene and its derivatives. More accurately, it is used to classify any compound that meets the Hückel criteria for aromaticity (Section 21.2A).
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aromatic hydrocarbon.
A hydrocarbon that contains one or more benzene rings. (24.1)
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bimolecular
For mechanisms, a step that involves two chemical entities.
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charcoal
A form of carbon produced when wood is heated strongly in a deficiency of air. (Section 22.9)
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Condensation polymerization
A polymerization in which chain growth occurs in a stepwise manner between difunctional monomers. Also called step-growth polymerization.
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dextrorotatory
A compound that rotates plane-polarized light in a clockwise direction (+).
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Dihedral angle
The angle created by two intersecting planes.
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electron configuration
The arrangement of electrons in the orbitals of an atom or molecule (Section 6.8)
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elimination
A reaction involving the loss of a leaving group and formation of a p bond.
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heat of fusion
The enthalpy change, ?H, for melting a solid. (Section 11.4)
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Imide
A functional group in which two acyl groups, RCO! or ArCO!, are bonded to a nitrogen atom
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kinetic-molecular theory
A set of assumptions about the nature of gases. These assumptions, when translated into mathematical form, yield the ideal-gas equation. (Section 10.7)
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Step-growth polymerization
A polymerization in which chain growth occurs in a stepwise manner between difunctional monomers as, for example, between adipic acid and hexamethylenediamine to form nylon 66. Also called condensation polymerization.
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Triol
A compound containing three hydroxyl groups.
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Valence-shell electron-pair repulsion (VSEPR)
A method for predicting bond angles based on the idea that electron pairs repel each other and keep as far apart as possible.