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Solutions for Chapter 13: Mass Spectrometry and Infrared Spectroscopy

Organic Chemistry | 3rd Edition | ISBN: 9780077354725 | Authors: Janice Gorzynski Smith

Full solutions for Organic Chemistry | 3rd Edition

ISBN: 9780077354725

Organic Chemistry | 3rd Edition | ISBN: 9780077354725 | Authors: Janice Gorzynski Smith

Solutions for Chapter 13: Mass Spectrometry and Infrared Spectroscopy

Solutions for Chapter 13
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Textbook: Organic Chemistry
Edition: 3
Author: Janice Gorzynski Smith
ISBN: 9780077354725

Since 49 problems in chapter 13: Mass Spectrometry and Infrared Spectroscopy have been answered, more than 65010 students have viewed full step-by-step solutions from this chapter. This textbook survival guide was created for the textbook: Organic Chemistry, edition: 3. Organic Chemistry was written by and is associated to the ISBN: 9780077354725. Chapter 13: Mass Spectrometry and Infrared Spectroscopy includes 49 full step-by-step solutions. This expansive textbook survival guide covers the following chapters and their solutions.

Key Chemistry Terms and definitions covered in this textbook
  • acid-catalyzed hydration

    A reaction that achieves the addition of water across a double bond in the presence of an acid catalyst.

  • alloy

    A substance that has the characteristic properties of a metal and contains more than one element. Often there is one principal metallic component, with other elements present in smaller amounts. Alloys may be homogeneous or heterogeneous. (Section 12.3)

  • autooxidation

    The slow oxidation of organic compounds that occurs in the presence of atmospheric oxygen.

  • bar

    A unit of pressure equal to 105 Pa. (Section 10.2)

  • Chiral center

    A tetrahedral atom, most commonly carbon, that is bonded to four different groups; also called a chirality center

  • Cis

    A prefi x meaning on the same side

  • diamagnetic.

    Repelled by a magnet; a diamagnetic substance contains only paired electrons. (7.8)

  • diamagnetism

    A type of magnetism that causes a substance with no unpaired electrons to be weakly repelled from a magnetic field. (Section 9.8)

  • exo

    In Diels-Alder reactions that produce bicyclic structures, the positions that are anti to the larger bridge.

  • frontier orbital theory

    The analysis of a reaction using MO theory, where only the frontier orbitals (HOMO and LUMO) are considered.

  • Ionization potential (IP)

    The minimum energy required to remove an electron from an atom or molecule to a distance where there is no electrostatic interaction between the resulting ion and electron.

  • lattice points

    Points in a crystal all of which have identical environments. (Section 12.2)

  • Levorotatory

    Refers to a substance that rotates the plane of polarized light to the left.

  • loss of a leaving group

    One of the four arrow-pushing patterns for ionic reactions.

  • mercurinium ion

    The intermediateformed during oxymercuration.

  • n+1 rule

    In NMR spectroscopy, if n is the number of neighboring protons, then the multiplicity will be n+1.

  • Raoult’s law

    A law stating that the partial pressure of a solvent over a solution, Psolution, is given by the vapor pressure of the pure solvent, P° solvent, times the mole fraction of a solvent in the solution, Xsolvent: Psolution = XsolventP° solvent. (Section 13.5)

  • substitution reactions

    Reactions in which one group is replaced by another group.

  • twist boat

    A conformation of cyclohexane that is lower in energy than a boat conformation but higher in energy than a chair conformation.

  • Twist-boat conformation

    A nonplanar conformation of a cyclohexane ring that is twisted from and slightly more stable than a boat conformation.

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