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Solutions for Chapter 26: CarbonCarbon Bond-Forming Reactions in Organic Synthesis

Organic Chemistry | 3rd Edition | ISBN: 9780077354725 | Authors: Janice Gorzynski Smith

Full solutions for Organic Chemistry | 3rd Edition

ISBN: 9780077354725

Organic Chemistry | 3rd Edition | ISBN: 9780077354725 | Authors: Janice Gorzynski Smith

Solutions for Chapter 26: CarbonCarbon Bond-Forming Reactions in Organic Synthesis

Solutions for Chapter 26
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Textbook: Organic Chemistry
Edition: 3
Author: Janice Gorzynski Smith
ISBN: 9780077354725

This expansive textbook survival guide covers the following chapters and their solutions. Chapter 26: CarbonCarbon Bond-Forming Reactions in Organic Synthesis includes 45 full step-by-step solutions. Organic Chemistry was written by and is associated to the ISBN: 9780077354725. Since 45 problems in chapter 26: CarbonCarbon Bond-Forming Reactions in Organic Synthesis have been answered, more than 62590 students have viewed full step-by-step solutions from this chapter. This textbook survival guide was created for the textbook: Organic Chemistry, edition: 3.

Key Chemistry Terms and definitions covered in this textbook
  • Alditol

    The product formed when the C"O group of a monosaccharide is reduced to a CHOH group.

  • Anti stereoselectivity

    The addition of atoms or groups of atoms to opposite faces of a carbon-carbon double bond.

  • Axial bond

    A bond to a chair conformation of cyclohexane that extends from the ring parallel to the imaginary axis through the center of the ring; a bond that lies roughly perpendicular to the equator of the ring.

  • beta (b) anomer

    The cyclic hemiacetal of an aldose, in which the hydroxyl group at the anomeric position is cis to the CH2OH group.

  • beta elimination

    An elimination reaction in which a proton from the beta (b) position is removed together with the leaving group, forming a double bond.

  • Bicycloalkane

    An alkane containing two rings that share two carbons

  • Brønsted-Lowry acid

    A proton donor

  • condensation reaction.

    A reaction in which two smaller molecules combine to form a larger molecule. Water is invariably one of the products of such a reaction. (24.4)

  • Conjugated

    A conjugated diene or carbonyl is one in which the double bonds are separated by one single bond

  • effusion

    The escape of a gas through an orifice or hole. (Section 10.8)

  • intermediate

    A substance formed in one elementary step of a multistep mechanism and consumed in another; it is neither a reactant nor an ultimate product of the overall reaction. (Section 14.6)

  • ion-product constant

    For water, Kw is the product of the aquated hydrogen ion and hydroxide ion concentrations: 3H+43OH-4 = Kw = 1.0 * 10-14 at 25 °C. (Section 16.3)

  • ligand

    An ion or molecule that coordinates to a metal atom or to a metal ion to form a complex. (Section 23.2)

  • Markovnikov’s rule

    In the addition of HX, H2O, or ROH to an alkene, hydrogen adds to the carbon of the double bond having the greater number of hydrogens.

  • oxidation state

    A method of electron book-keeping in which all bonds are treated as if they were purely ionic.

  • ozone

    The name given to O3, an allotrope of oxygen. (Section 7.8)

  • Polyurethane

    A polymer containing the !NHCO2! group as a repeating unit

  • SN1

    A unimolecular nucleophilic substitution reaction.

  • vibrational excitation

    In IR spectroscopy, the energy of a photon is absorbed and temporarily stored as vibrational energy

  • Wittig reagent

    A reagent used to perform a Wittig reaction.

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