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Solutions for Chapter 26: CarbonCarbon Bond-Forming Reactions in Organic Synthesis

Organic Chemistry | 3rd Edition | ISBN: 9780077354725 | Authors: Janice Gorzynski Smith

Full solutions for Organic Chemistry | 3rd Edition

ISBN: 9780077354725

Organic Chemistry | 3rd Edition | ISBN: 9780077354725 | Authors: Janice Gorzynski Smith

Solutions for Chapter 26: CarbonCarbon Bond-Forming Reactions in Organic Synthesis

Solutions for Chapter 26
4 5 0 310 Reviews
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Textbook: Organic Chemistry
Edition: 3
Author: Janice Gorzynski Smith
ISBN: 9780077354725

This expansive textbook survival guide covers the following chapters and their solutions. Chapter 26: CarbonCarbon Bond-Forming Reactions in Organic Synthesis includes 45 full step-by-step solutions. Organic Chemistry was written by and is associated to the ISBN: 9780077354725. Since 45 problems in chapter 26: CarbonCarbon Bond-Forming Reactions in Organic Synthesis have been answered, more than 221478 students have viewed full step-by-step solutions from this chapter. This textbook survival guide was created for the textbook: Organic Chemistry, edition: 3.

Key Chemistry Terms and definitions covered in this textbook
  • 1,2-elimination

    An elimination reaction in which a proton from the beta (b) position is removed together with the leaving group, forming a double bond.

  • amphoteric

    Compounds that will react with either acids or bases. Amino acids are amphoteric.

  • auxochrome

    When applying Woodward-Fieser rules, the groups attached to the chromophore.

  • base peak

    In mass spectrometry, the tallest peak in the spectrum, which is assigned a relative value of 100%.

  • closed system.

    A system that enables the exchange of energy (usually in the form of heat) but not mass with its surroundings. (6.2)

  • E2

    A bimolecular eliminationreaction.eclipsed conformation (Sect. 4.7): A conformationin which groups are eclipsing each other in aNewman projection.

  • endothermic

    Any process with a positive DH (the system receives energy from the surroundings).

  • Haworth projection

    For substituted cycloalkanes, a drawing style used to clearly identify which groups are above the ring and which groups are below the ring. (See also Sect. 4.14.)

  • Heat of reaction (DH0 )

    The difference in enthalpy between reactants and products. If the enthalpy of products is lower than that of the reactants, heat is released and the reaction is exothermic. If the enthalpy of the products is higher than that of the reactants, energy is absorbed, and the reaction is endothermic

  • Homotopic groups

    Atoms or groups on an atom that give an achiral molecule when one of the groups is replaced by another group. The hydrogens of the CH2 group of propane, for example, are homotopic. Replacing either one of them with deuterium gives 2-deuteropropane, which is achiral. Homotopic groups have identical chemical shifts under all conditions

  • ionic compound

    A compound composed of cations and anions. (Section 2.7)

  • Low-density lipoprotein (LDL)

    Plasma particles, density 1.02–1.06 g/mL, consisting of approximately 26% proteins, 50% cholesterol, 21% phospholipids, and 4% triglycerides.

  • Melt transition (Tm)

    The temperature at which crystalline regions of a polymer melt.

  • normal melting point

    The melting point at 1 atm pressure. (Section 11.6)

  • Pauli exclusion principle

    No more than two electrons may be present in an orbital. If two electrons are present, their spins must be paired

  • Polymer

    From the Greek, poly 1 meros, meaning many parts. Any long-chain molecule synthesized by linking together many single parts called monomers

  • reaction mechanism

    A series of intermediates and curved arrows that show howthe reaction occurs in terms of the motion of electrons.

  • Reductive elimination

    Elimination of two substituents at a metal center, causing the oxidation state of the metal to decrease by two.

  • Tautomers

    Constitutional isomers in equilibrium with each other that differ in the location of a hydrogen atom and a double bond relative to a heteroatom, most commonly O, N, or S.

  • tetrahedral

    The geometry of an atom with four bonds separated from each other by 109.5°.