Principles of Instrumental Analysis 6th Edition - Solutions by Chapter

An organic compound obtained by substituting a hydroxyl group 1¬OH2 for a hydrogen on a hydrocarbon. (Sections 2.9 and 24.4)

A solid solution composed of two or more metals, or of a metal or metals with one or more nonmetals. (21.2)

An equilibrium constant that expresses the extent to which a base reacts with solvent water, accepting a proton and forming OH-1aq2. (Section 16.7)

A structure containing two rings that are fused together.

A voltaic cell containing the same electrolyte and the same electrode materials in both the anode and cathode compartments. The emf of the cell is derived from a difference in the concentrations of the same electrolyte solutions in the compartments. (Section 20.6)

Theresulting net attraction between two dipoles.

A three-dimensional, rainbowlike image used to visualize partial charges in a compound.

The measure of disorder associated with a system.

The temperature at which the crystallineregions of a polymer become amorphous.

In NMR spectroscopy, a technique in which only the one-bond couplings are observed. CH3 groups appear as quartets, CH2 groups appear as triplets, CH groups appear as doublets, and quaternary carbon atoms appear as singlets.

The extent to which atomic orbitals on different atoms share the same region of space. When the overlap between two orbitals is large, a strong bond may be formed. (Section 9.4)

Properties that can be measured without changing the composition of a substance, for example, color and freezing point. (Section 1.3)

A macromolecule containing many amino acid units, each joined to the next by a peptide bond

Work performed by expansion of a gas against a resisting pressure. (Section 5.3)

The stabilization associated with the delocalization of electrons via resonance.

The reverse of a Diels-Alder reaction, achieved at high temperature. A cyclohexene derivative is converted into a diene and a dienophile.

Atomic orbitals that are achieved by mathematically averaging one s orbital with two p orbitals to form three hybridized atomic orbitals.

The weighted averages for each element, which takes into account isotopic abundance.

In nomenclature, the groups connected to the parent chain.

A nonplanar conformation of a cyclohexane ring that is twisted from and slightly more stable than a boat conformation.