Principles of Instrumental Analysis 6th Edition - Solutions by Chapter

Specific site on a heterogeneous catalyst or an enzyme where catalysis occurs. (Section 14.7)

Stereoisomeric cyclic hemiacetals of an aldose or ketose that differ from each other in their configuration at the anomeric carbon.

A molecular orbital that is of higher energy and lower stability than the atomic orbitals from which it was formed. (10.6)

A statement that equal volumes of gases at the same temperature and pressure contain equal numbers of molecules. (Section 10.3)

See beta rays.

The generally larger formation constants for polydentate ligands as compared with the corresponding monodentate ligands. (Section 23.3)

A nucleophilic acyl substitution reaction in which the nucleophile is an ester enolate and the electrophile is an ester.

A situation in which two or more orbitals have the same energy. (Section 6.7)

A model for the behavior of electrons in metals. (Section 12.4)

The enthalpy change that accompanies the formation of a substance from the most stable forms of its component elements. (Section 5.7)

The process of forming an ester by refl uxing a carboxylic acid and an alcohol in the presence of an acid catalyst, commonly H2SO4, ArSO3H, or HCl

An organic compound containing at least one halogen.

A drawing style inwhich the electrons take center stage.linear polymer (Sect. 27.6): A polymer thathas only a minimal amount of branching or nobranching at all.

A compound with molecular formula HONO.

An instrument for measuring the ability of a compound to rotate the plane of plane-polarized light.

A measure of the ease of distortion of the distribution of electron density about an atom or group in response to interaction with other molecules or ions. Fluorine which has a high electronegativity and holds its electrons tightly, has a very low polarizability. Iodine, which has a lower electronegativity and holds its electrons less tightly, has a very high polarizability.

Lipids that contain 20 carbon atoms and are characterized by a five-membered ring with two side chains.

Defined as 760 torr or, in SI units, 101.325 kPa. (Section 10.2)

A compound that contains two SR groups, both of which are connected to the same carbon atom.

The minimum distance of approach to an atom that does not cause nonbonded interaction strain.