- 6.6-1: Define(a) coherent radiation(b) dispersion of a transparent substan...
- 6.6-2: Calculate the frequency in hertz, the energy in joules, and the enc...
- 6.6-3: Calculate the frequcncy in hertz, the wavenumber, the energy in jou...
- 6.6-4: Calculate the wavelength and the energy in joules associated with a...
- 6.6-5: Calculate the velocity, frequcncy, and wavelength of the sodium D l...
- 6.6-6: 6 When the D line of sodium light impinges an air-diamond interface...
- 6.6-7: What is the wavelength of a photon that has three times as much ene...
- 6.6-8: The silver iodide bond energy is approximately 255 kllmol (AgI is o...
- 6.6-9: Cesium is used extensively in photocells and in television cameras ...
- 6.6-10: The Wien displacement law for blackbody radiators states that the p...
- 6.6-11: 1 Calculate the wavelength of(a) the sodium line at 589 nm in honey...
- 6.6-12: Calculate the reflection loss when a beam of radiant energy passes ...
- 6.6-13: Explain why the wave model for radiation cannot account for the pho...
- 6.6-14: Convert the following absorbance data into percent transmittance:(a...
- 6.6-15: Convert the following percent transmittance data into absorbance:(a...
- 6.6-16: Calculate the percent transmittance of solutions with half the abso...
- 6.6-17: Calculate the absorbance of solutions with half the percent transmi...
- 6.6-18: A solution that was 3.78 X 10-3 M in X had a transmittance of 0.212...
- 6.6-19: A compound had a molar absorptivity of 3.03 x 10.1L cm-I mol-I. Wha...
- 6.6-20: One of the watershed events in the development of physics and chemi...
- 6.7-21: Distinguish among (a) a spectroscope, (b) a spectrograph, and (c) a...
- 6.7-22: A Michelson interferometer had a mirror \'elocity of 2.75 cm/s. Wha...
- 6.7-23: What length of mirror drive in a Michelson interferometer is requir...
- 6.7-24: The behavior of holographic filters and gratings is described by co...
Solutions for Chapter 6: An Introduction to Spectrometric Methods
Full solutions for Principles of Instrumental Analysis | 6th Edition
An amino acid in which the amino group is on the carbon adjacent to the carboxyl group.
Specific site on a heterogeneous catalyst or an enzyme where catalysis occurs. (Section 14.7)
alpha (a) position
The position immediately adjacent to a functional group.
Antibonding molecular orbital
A molecular orbital in which electrons have a higher energy than they would in isolated atomic orbitals
The breaking of a bond, either homolytically or heterolytically. bond dissociation energy (Sect. 6.1): The energy required to achieve homolytic bond cleavage (generating radicals).
The cycle that relates lattice energies of ionic compounds to ionization energies, electron affinities, heats of sublimation and formation, and bond enthalpies. (9.3)
The number of times the cycle of chain propagation steps repeats in a chain reaction.
Chlorofl uorocarbons (CFCs, Freons)
Compounds with one or two carbons, chlorine, and fl uorine, formerly used as refrigerants
The species formed when an acid transfers a proton to a base
Orbitals that have the same energy.
dipole moment (m)
The amount of partial charge (d ) on either end of a dipole multiplied by the distance of separation (d): m=d × d
The escape of a gas through an orifice or hole. (Section 10.8)
The highest occupied molecular orbital.
Molar absorptivity (e)
The absorbance of a 1 M solution of a compound.
The product formed when either d-ribose or 2-deoxy-d-ribose is coupled with certain nitrogen heterocycles (called bases).
A reaction that involves the participation of ions as reactants, intermediates, or products.
A measure of the salt content of seawater, brine, or brackish water. It is equal to the mass in grams of dissolved salts present in 1 kg of seawater. (Section 18.3)
A solution in which undissolved solute and dissolved solute are in equilibrium. (Section 13.2)
Shielding in NMR
Also called diamagnetic shielding; the term refers to the reduction in magnetic fi eld strength experienced by a nucleus underneath electron density induced to circulate when the molecule is placed in a strong magnetic fi eld.
An ether (R!O!R) where both R groups are identical.
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