- 14.14-1: A 25.0-mL aliquot of an aqueous quinine solution was diluted to 50....
- 14.14-2: A 0.5990-g pesticide sample was decomposed by wet ashing and then d...
- 14.14-3: Sketch a photometric titration curve for the titration of SnHwith M...
- 14.14-4: Iron(IIl) reacts with thiocyanate ion to form the red complex Fe(SC...
- 14.14-5: 5 Ethylenediaminetetraacetic acid abstracts bismuth(IIl) from its t...
- 14.14-6: The accompanying data (l.OO-cm cells) were ohtained for the spectro...
- 14.14-7: A 3.65-g petroleum specimen was decomposed by wet ashing and subseq...
- 14.14-8: A simultaneous detcrmination for cohalt and nickel can he hased on ...
- 14.14-9: When measured with a 1.00-cm cell, a 7.50 X 105 M solution of speci...
- 14.14-10: The acid-base indicator Hln undergoes the following reaction in dil...
- 14.14-11: A standard solution was put through appropriate dilutions to give t...
- 14.14-12: The method developed in 14-11 was used for the routine detcrminatio...
- 14.14-13: Copper(II) forms a 1: 1 complcx with the organic complexing agent R...
- 14.14-14: Aluminum forms a I: I complex with 2-hydroxy-lnaphthaldehyde p-meth...
- 14.14-15: The enzyme monoamine oxidase catalyzes the oxidation of amines to a...
- 14.14-16: The sodium salt of 2-quinizarinsulfonic acid (NaQ) forms a complex ...
- 14.14-17: The accompanying data were obtained in a slope-ratio investigation ...
- 14.14-18: The accompanying absorption data were recorded at 390 nm in 1.00-cm...
- 14.14-19: Palladium(II) forms an intensely colored complex at pH 3.5 with ars...
- 14.14-20: Given the information thatFe3+ + y4- ~ FeY- K, = 1.0 X 10"Cu" + y4-...
- 14.14-21: 1 The chelate CuA,2- exhibits maximum absorption at 480 nm. When th...
- 14.14-22: Mixing the chelating reagent B with Ni(I1) forms the highly colored...
- 14.14-23: To determine the formation constant of a I: 1 complex. the absorban...
- 14.14-24: (a) Prove mathematically that the peak in a continuous-variations p...
Solutions for Chapter 14: Applications of Ultraviolet -Visible Molecular Absorption SpectrQmetry
Full solutions for Principles of Instrumental Analysis | 6th Edition
Solutions for Chapter 14: Applications of Ultraviolet -Visible Molecular Absorption SpectrQmetryGet Full Solutions
The resonancestabilized, cationic intermediate of a Friedel-Crafts acylation, formed by treating an acyl halide with aluminum trichloride.
An organic compound containing the hydroxyl group —OH. (24.4)
A compound that contains at least one amino group and at least one carboxyl group. (25.3)
A common non-SI unit of length, denoted Å, that is used to measure atomic dimensions: 1Å = 10-10 m. (Section 2.3)
A substance that is an H+ acceptor; a base produces an excess of OH-1aq2 ions when it dissolves in water. (Section 4.3)
A crystal lattice in which the lattice points are located at the center and corners of each unit cell. (Section 12.2)
The distance between the centers of two bonded atoms. (Section 8.3)
A separation method involving passing a vapor or solution mixture through a column packed with a material with different affi nities for different components of the mixture.
complete ionic equation
A chemical equation in which dissolved strong electrolytes (such as dissolved ionic compounds) are written as separate ions. (Section 4.2)
degree of substitution
For alkenes, a classification method that refers to the number of alkyl groups connected to the double bond.
A termination process that involves the abstraction of a hydrogen atom from the beta position of the propagating radical of one chain by the radical endgroup of another chain.
A drawing style that is often used when dealing with compounds bearing multiple chirality centers, especially for carbohydrates. (See also Sect. 5.7.)
The combination of atomic orbitals of different types
For a peptide chain,the end that contains the amino group.
A system for naming organic compounds.
polar covalent bond
A bond in which the difference in electronegative values of the two atoms is between 0.5 and 1.7.
quaternary ammonium salt
An ionic compound containing a positively charged nitrogen atom connected to four alkyl groups.
resonance structures (resonance forms)
Individual Lewis structures in cases where two or more Lewis structures are equally good descriptions of a single molecule. The resonance structures in such an instance are “averaged” to give a more accurate description of the real molecule. (Section 8.6)
A reaction that has a rate equation in which the sum of all exponents is three
For alkenes, a stereodescriptor that indicates that the two priority groups are on the same side of the p bond.