- 14.14-1: A 25.0-mL aliquot of an aqueous quinine solution was diluted to 50....
- 14.14-2: A 0.5990-g pesticide sample was decomposed by wet ashing and then d...
- 14.14-3: Sketch a photometric titration curve for the titration of SnHwith M...
- 14.14-4: Iron(IIl) reacts with thiocyanate ion to form the red complex Fe(SC...
- 14.14-5: 5 Ethylenediaminetetraacetic acid abstracts bismuth(IIl) from its t...
- 14.14-6: The accompanying data (l.OO-cm cells) were ohtained for the spectro...
- 14.14-7: A 3.65-g petroleum specimen was decomposed by wet ashing and subseq...
- 14.14-8: A simultaneous detcrmination for cohalt and nickel can he hased on ...
- 14.14-9: When measured with a 1.00-cm cell, a 7.50 X 105 M solution of speci...
- 14.14-10: The acid-base indicator Hln undergoes the following reaction in dil...
- 14.14-11: A standard solution was put through appropriate dilutions to give t...
- 14.14-12: The method developed in 14-11 was used for the routine detcrminatio...
- 14.14-13: Copper(II) forms a 1: 1 complcx with the organic complexing agent R...
- 14.14-14: Aluminum forms a I: I complex with 2-hydroxy-lnaphthaldehyde p-meth...
- 14.14-15: The enzyme monoamine oxidase catalyzes the oxidation of amines to a...
- 14.14-16: The sodium salt of 2-quinizarinsulfonic acid (NaQ) forms a complex ...
- 14.14-17: The accompanying data were obtained in a slope-ratio investigation ...
- 14.14-18: The accompanying absorption data were recorded at 390 nm in 1.00-cm...
- 14.14-19: Palladium(II) forms an intensely colored complex at pH 3.5 with ars...
- 14.14-20: Given the information thatFe3+ + y4- ~ FeY- K, = 1.0 X 10"Cu" + y4-...
- 14.14-21: 1 The chelate CuA,2- exhibits maximum absorption at 480 nm. When th...
- 14.14-22: Mixing the chelating reagent B with Ni(I1) forms the highly colored...
- 14.14-23: To determine the formation constant of a I: 1 complex. the absorban...
- 14.14-24: (a) Prove mathematically that the peak in a continuous-variations p...
Solutions for Chapter 14: Applications of Ultraviolet -Visible Molecular Absorption SpectrQmetry
Full solutions for Principles of Instrumental Analysis | 6th Edition
Solutions for Chapter 14: Applications of Ultraviolet -Visible Molecular Absorption SpectrQmetryGet Full Solutions
Members of group 1A in the periodic table. (Section 7.7)
A conformation about a single bond in which two groups on adjacent carbons lie at a dihedral angle of 180°.
A method for preparing primary amines that avoids the formation of secondary and tertiary amines.
boiling-point elevation (DTb).
The boiling point of the solution (Tb) minus the boiling point of the pure solvent (T° b). (12.6)
The lowest energy conformation for cyclohexane, in which all bond angles are fairly close to 109.5° and all hydrogen atoms are staggered.
The species formed when an acid transfers a proton to a base
coupling (of protons)
A phenomenon observed most commonly for nonequivalent protons connected to adjacent carbon atoms in which the multiplicity of each signal is affected by the other.
A carbohydrate for whichthe chirality center farthest from the carbonylgroup will have an OH group pointing to theright in the Fischer projection.
A symbol used to show that structures on either side of it are resonance-contributing structures
Proteins that consist of linear chains that are bundled together.
The splitting of a large nucleus into two smaller ones. (Section 21.6)
The bond from the anomeric carbon of a glycoside to an !OR group
An effect that explains why alkyl groups stabilize a carbocation.
A compound containing a five-membered ring that is similar to pyrrole but has one extra nitrogen atom at the 3 position.
isoelectric point (pI)
For an amino acid, the specific pH at which the concentration of the zwitterionic form reaches its maximum value.
The process that occurs in plant leaves by which light energy is used to convert carbon dioxide and water to carbohydrates and oxygen. (Section 23.3)
A change in connectivity of the atoms in a product compared with the con nectivity of the same atoms in the starting material.
Lipids that are based on a tetracyclic ring system involving three six-membered rings and one five-membered ring. Cholesterol is an example.
Compounds containing a mercapto group (SH).
An ester of glycerol with three fatty acids