- 22.22-1: Calculate the electrode potentials of the following half-cells.(a) ...
- 22.22-2: Calculate the electrode potentials of the following half-cells.(a) ...
- 22.22-3: For each of the following half-cells, comparc electrode potentials ...
- 22.22-4: For each of the following half-cclls, compare electrode potentials ...
- 22.22-5: Calculate the potential of a silver electrode in contact with the f...
- 22.22-6: Calculate the electrode potentials for the following systems:(a) Cr...
- 22.22-7: Calculate the theoretical potential of each of the following cells....
- 22.22-8: Calculate the theoretical potential of each of the following cells....
- 22.22-9: Compute EO for the processNi(CN)}- + 2e' ~ Ni(s) + 4CWgiven that th...
- 22.22-10: The solubility product constant for Pb[, is 7.1 x 10-9at 25"C. Calc...
- 22.22-11: Calculate the standard potential for the half-reaction
- 22.22-12: Calculate the standard potential for the half-reaction AI(C,O.),' +...
- 22.22-13: From the standard potentialsTI+ + e- ~TI(s) 0 = -0.336 VTICl(s) + e...
- 22.22-14: From the standard potentialsAg,SeO.(s) + 2e' ~ 2Ag(s) + SeO,' E" = ...
- 22.22-15: Suppose that we wish to produce a current of 0.0750 A in the cellPt...
- 22.22-16: The cellPtIY(OHl:(2.67 x 1O-'M),vO"(3.42 x lO-'Ml.H'(4.81 x 10-' Ml...
- 22.22-17: The resistance of the galvanic cellPtIFe(CN):-(4.42 X 1O-'M),Fe(CNl...
- 22.22-18: The following data are similar to those given in Example 22-1.(a) C...
- 22.22-19: As a part of a study to measure the dissociation constant of acetic...
- 22.22-20: As we saw in 22-19, as a preliminary experiment in their effort to ...
Solutions for Chapter 22: An Introduction to Electroanalytical Chemistry
Full solutions for Principles of Instrumental Analysis | 6th Edition
Element in which the 5f orbitals are only partially occupied. (Section 6.8)
alpha (a) anomer
The cyclic hemiacetal of an aldose in which the hydroxyl group at the anomeric position is trans to the CH2OH
A steroid hormone, such as testosterone, that promotes tissue and muscle growth and development
At constant pressure and temperature, the volume of a gas is directly proportional to the number of moles of the gas present. (5.3)
A type of polypeptide secondary structure in which sections of polypeptide chains are aligned parallel or antiparallel to one another.
A substance that yields hydroxide ions (OH2) when dissolved in water. (2.7)
The transfer of reactivity of an endgroup from one chain to another during a polymerization
The area of chemistry concerned with the speeds, or rates, at which chemical reactions occur. (13.1)
Compound containing only carbon, chlorine, and fluorine.
The electrons that are not in the outermost shell of an atom. (Section 6.8)
The removal of salts from seawater, brine, or brackish water to make it fit for human consumption. (Section 18.4)
A unimolecular elimination reaction.
A compound containing a hydroxyl group (OH) and an alkoxy group (OR) connected to the same carbon atom.
A collection of Avogadro’s number 16.022 * 10232 of objects; for example, a mole of H2O is 6.022 * 1023 H2O molecules. (Section 3.4)
The change in specifi c rotation that occurs when an a or b hemiacetal form of a carbohydrate in aqueous solution is converted to an equilibrium mixture of the two forms.
parts per billion (ppb)
The concentration of a solution in grams of solute per 109 (billion) grams of solution; equals micrograms of solute per liter of solution for aqueous solutions. (Section 13.4)
Cleavage by light.
Principle of microscopic reversibility
This principle states that the sequence of transition states and reactive intermediates in the mechanism of any reversible reaction must be the same, but in reverse order, for the reverse reaction as for the forward reaction
A compound that contains two SR groups, both of which are connected to the same carbon atom.
A reaction that converts an aldehyde or ketone into an alkene, with the introduction of one or more carbon atoms.