- 184.108.40.206: The following questions relate to a cyclohexane ring in the chair c...
- 220.127.116.11: Draw the most stable conformation of 1-tert-butyl-1-methylcyclohexane.
Solutions for Chapter 3.10: Conformational Analysis of Monosubstituted Cyclohexanes
Full solutions for Organic Chemistry, | 9th Edition
Solutions for Chapter 3.10: Conformational Analysis of Monosubstituted CyclohexanesGet Full Solutions
The decay rate of a radioactive material, generally expressed as the number of disintegrations per unit time. (Section 21.4)
The addition of atoms or groups of atoms to opposite faces of a carbon-carbon double bond.
Benzyl group (C6H5CH2!)
The group derived from toluene by removing a hydrogen from its methyl group.
A reactive intermediate formed by b-elimination from adjacent carbon atoms of a benzene ring and having a triple bond in the benzene ring. The second p bond of the benzyne triple bond is formed by the weak overlap of coplanar 2p orbitals on adjacent carbons.
See beta rays.
A process by which molecular oxygen is used to convert food into CO2, water, and energy.
Addition of a nucleophile to the b-carbon of an a,b-unsaturated carbonyl compound. (Section 20.2A) Addition to carbons 1 and 4 of a conjugated diene.
critical pressure (Pc).
The minimum pressure necessary to bring about liquefaction at the critical temperature. (11.8)
A material that can undergo a substantial change in shape via stretching, bending, or compression and return to its original shape upon release of the distorting force. (Section 12.6)
A compound containing a hydroxyl group bonded to a doubly bonded carbon atom.
A reaction in which the Gibbs free energy of the products is lower than that of the reactants. The position of equilibrium for an exergonic reaction favors products.
Long-chain carboxylic acids.
An electrophilic aromatic substitution in which a hydrogen of an aromatic ring is replaced by an alkyl or acyl group.
lithium dialkyl cuprate
A nucleophilic compound with the general structureR2CuLi.
loss of a leaving group
One of the four arrow-pushing patterns for ionic reactions.
Molecular dipole moment (m)
The vector sum of individual bond dipoles.
A constant of proportionality between the reaction rate and the concentrations of reactants that appear in the rate law. (Section 14.3)
A test for determining the relationship between two protons. The compound is drawn two times, each time replacing one of the protons with deuterium. If the two compounds are identical, the protons are homotopic. If the two compounds are enantiomers, the protons are enantiotopic. If the two compounds are diastereomers, the protons are diastereotopic.
standard atomic weight
The weighted averages for each element, which takes into account isotopic abundance.
Williamson ether synthesis
A general method for the synthesis of dialkyl ethers by an SN2 reaction between a haloalkane and an alkoxide ion.