Solutions for Chapter 5.16: Anti Elimination in E2 Reactions: Stereoelectronic Effects
Full solutions for Organic Chemistry, | 9th Edition
Solutions for Chapter 5.16: Anti Elimination in E2 Reactions: Stereoelectronic EffectsGet Full Solutions
alpha (a) anomer
The cyclic hemiacetal of an aldose in which the hydroxyl group at the anomeric position is trans to the CH2OH
A steroid hormone, such as testosterone, that mediates the development of sexual characteristics of males.
For chair conformations of substituted cyclohexanes, a position that is parallel to a vertical axis passing through the center of the ring.
A derivative of a carboxylic acid in which H of the carboxyl group is replaced by a carbon.
A tetrahedral atom, most commonly carbon, that is bonded to four different groups; also called a chirality center
A compound in which two p bonds are separated from each other by exactly one s bond.
The spreading of one substance through a space occupied by one or more other substances. (Section 10.8)
In NMR spectroscopy, a signal that is comprised of two peaks.
The point in a titration at which the added solute reacts completely with the solute present in the solution. (Section 4.6)
exchange (metathesis) reaction
A reaction between compounds that when written as a molecular equation appears to involve the exchange of ions between the two reactants. (Section 4.2)
frontier orbital theory
The analysis of a reaction using MO theory, where only the frontier orbitals (HOMO and LUMO) are considered.
hydrogen deficiency index (HDI)
A measure of the number of degrees of unsaturation in a compound.
A nonpolar group that does not have favorable interactions with water.
isoelectric point (pI)
For an amino acid, the specific pH at which the concentration of the zwitterionic form reaches its maximum value.
molecular orbital (MO)
An allowed state for an electron in a molecule. According to molecular-orbital theory, a molecular orbital is entirely analogous to an atomic orbital, which is an allowed state for an electron in an atom. Most bonding molecular orbitals can be classified as s or p, depending on the disposition of electron density with respect to the internuclear axis. (Section 9.7)
When used in the context of fats and oils, a mixture of triglycerides that is liquid at room temperature
The ability of an atom or molecule to distribute its electron density unevenly in response to external influences.
radioactive decay chain
A series of nuclear reactions that begins with an unstable nucleus and terminates with a stable one. Also called nuclear disintegration series. (Section 21.2)
An addition or substitution reaction in which one of two or more possible products is formed in preference to all others that might be formed.
A reaction in which the overall reaction order (the sum of the concentration- term exponents) in the rate law is 2. (Section 14.4)