Solutions for Chapter 6.5: Carbocation Rearrangements in Hydrogen Halide Addition to Alkenes
Full solutions for Organic Chemistry, | 9th Edition
Solutions for Chapter 6.5: Carbocation Rearrangements in Hydrogen Halide Addition to AlkenesGet Full Solutions
The difference in Gibbs free energy between reactants and a transition state
Delocalized electrons move freely through “bands” formed by overlapping molecular orbitals. (21.3)
The angles made by the lines joining the nuclei of the atoms in a molecule. (Section 9.1)
A rule that states that it is not possible for a bridgehead carbon of a bicyclic system to possess a carbon carbon double bond if it involves a trans p bond being incorporated in a ring comprised of fewer than eight atoms.
Properties of solutions that depend on the number of solute particles in solution and not on the nature of the solute particles. (12.6)
An imaginary network of points on which the repeating motif of a solid may be imagined to be laid down so that the structure of the crystal is obtained. The motif may be a single atom or a group of atoms. Each lattice point represents an identical environment in the crystal. (Section 12.2)
A unit of measure fordipole moments, where 1 debye = 10-18 esu×cm.
A type of secondary structure of DNA molecules in which two anti parallel polynucleotide strands are coiled in a right-handed manner about the same axis
The charge on an atom in a polyatomic ion or molecule
Refers to a substance that rotates the plane of polarized light to the left.
Elements in the s and p blocks of the periodic table. (Section 6.9)
Nuclear magnetic resonance (NMR) spectroscopy
A spectroscopic technique that gives information about the number and types of atoms in a molecule, for example, hydrogens (1 H!NMR) and carbons (13C!NMR)
Pauli exclusion principle
A rule stating that no two electrons in an atom may have the same four quantum numbers (n, l, ml, and ms). As a reflection of this principle, there can be no more than two electrons in any one atomic orbital. (Section 6.7)
An instrument for measuring the ability of a compound to rotate the plane of plane-polarized light.
probability density 1c22
A value that represents the probability that an electron will be found at a given point in space. Also called electron density. (Section 6.5)
A compound that can be used to achieve the resolution of enantiomers.
A lipid that does not undergo hydrolysis in aqueous acid or base to produce smaller fragments.
Common leaving groups. Examples include tosylate, mesylate, and triflate ions.
A reaction that obeys conservation of orbital symmetry.
Cleavage by heating