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Solutions for Chapter 6.7: Thermodynamics of AdditionElimination Equilibria
Full solutions for Organic Chemistry, | 9th Edition
Theoretically the lowest attainable temperature. (5.3)
The conjugate base of acetylene or any terminal alkyne.
Benzyl group (C6H5CH2!)
The group derived from toluene by removing a hydrogen from its methyl group.
A species in which a carbon atom has only six electrons in its valence shell and bears a positive charge
A [3,3] sigmatropic rearrangement in which all six atoms of the cyclic transition state are carbon atoms.
Energy added or released when an electron is added to an atom or molecule.
In Diels-Alder reactions that produce bicyclic structures, the positions that are anti to the larger bridge.
A functional group in which two acyl groups, RCO! or ArCO!, are bonded to a nitrogen atom
Compounds formed when hydrogen reacts with alkali metals and also the heavier alkaline earths (Ca, Sr, and Ba); these compounds contain the hydride ion, H-. (Section 22.2)
In nomenclature, a numberused to identify the location of a substituent.
A chemical equation in which the formula for each substance is written without regard for whether it is an electrolyte or a nonelectrolyte. (Section 4.2)
A solid whose dimensions range from 1 to 100 nm and whose properties differ from those of a bulk material with the same composition. (Section 12.1)
Polymers of high molecular weight that carry genetic information and control protein synthesis. (Section 24.10)
In mass spectrometry,the ion that is generated when the compound is ionized.
For light, the orientation of the electric field.
A nuclear decay process where a positron, a particle with the same mass as an electron but with a positive charge, symbol 0+1e, or b+ is emitted from the nucleus. (Section 21.1)
Any chemical species that contains one or more unpaired electrons.
The power to which the concentration of a reactant is raised in a rate law. (Section 14.3)
Constitutional isomers that rapidly interconvert via the migration of a proton.
Williamson ether synthesis
A general method for the synthesis of dialkyl ethers by an SN2 reaction between a haloalkane and an alkoxide ion.