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Solutions for Chapter 10.13: Retrosynthetic Analysis and the DielsAlder Reaction

Organic Chemistry, | 9th Edition | ISBN: 9780073402741 | Authors: Francis A Carey Dr., Robert M. Giuliano

Full solutions for Organic Chemistry, | 9th Edition

ISBN: 9780073402741

Organic Chemistry, | 9th Edition | ISBN: 9780073402741 | Authors: Francis A Carey Dr., Robert M. Giuliano

Solutions for Chapter 10.13: Retrosynthetic Analysis and the DielsAlder Reaction

Solutions for Chapter 10.13
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This expansive textbook survival guide covers the following chapters and their solutions. Chapter 10.13: Retrosynthetic Analysis and the DielsAlder Reaction includes 2 full step-by-step solutions. Since 2 problems in chapter 10.13: Retrosynthetic Analysis and the DielsAlder Reaction have been answered, more than 36794 students have viewed full step-by-step solutions from this chapter. This textbook survival guide was created for the textbook: Organic Chemistry, , edition: 9. Organic Chemistry, was written by and is associated to the ISBN: 9780073402741.

Key Chemistry Terms and definitions covered in this textbook
  • antiferromagnetism

    A form of magnetism in which unpaired electron spins on adjacent sites point in opposite directions and cancel each other’s effects. (Section 23.1)

  • Atactic polymer

    A polymer with completely random confi gurations at the chiral centers along its chain, as, for example, atactic polypropylene

  • bromohydrin

    A compound containing a Br group and a hydroxyl group (OH) on adjacent carbon atoms.

  • Dehydrohalogenation

    Removal of !H and !X from adjacent carbons; a type of b-elimination

  • Electromagnetic radiation

    Light and other forms of radiant energy.

  • electrophoresis

    A technique for separating amino acids from each other based on a difference in pI values.

  • Enantioselective reaction

    A reaction that produces one enantiomer in preference to the other.

  • enol

    A compound containing a hydroxyl group (OH) connected directly to a carbon-carbon double bond.

  • gauche conformation

    A conformation that exhibits a gauche interaction.

  • Hofmann rule

    Any b-elimination that occurs preferentially to give the less substituted alkene as the major product.

  • hydrazone

    A compound with the structure R2CRN!NH2.

  • Lindlar catalyst

    Finely powdered palladium metal deposited on solid calcium carbonate that has been specially modifi ed with lead salts. Its particular use is as a catalyst for the reduction of an alkyne to a cis alkene

  • Low-density lipoprotein (LDL)

    Plasma particles, density 1.02–1.06 g/mL, consisting of approximately 26% proteins, 50% cholesterol, 21% phospholipids, and 4% triglycerides.

  • neutron

    An electrically neutral particle found in the nucleus of an atom; it has approximately the same mass as a proton. (Section 2.3)

  • primitive lattice

    A crystal lattice in which the lattice points are located only at the corners of each unit cell. (Section 12.2)

  • prostaglandins

    Lipids that contain 20 carbon atoms and are characterized by a five-membered ring with two side chains.

  • R

    A term used to designate the configuration of a chirality center, determined in the following way: Each of the four groups is assigned a priority, and the molecule is then rotated (if necessary) so that the #4 group is directed behind the page (on a dash). A clockwise sequence for 1-2-3 is designated as R.

  • reduction

    A process in which a substance gains one or more electrons. (Section 4.4)

  • standard atomic weight

    The weighted averages for each element, which takes into account isotopic abundance.

  • Z

    For alkenes, a stereodescriptor that indicates that the two priority groups are on the same side of the p bond.

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