Solutions for Chapter 11.16: Benzylic Side Chains and Retrosynthetic Analysis

Organic Chemistry, | 9th Edition | ISBN: 9780073402741 | Authors: Francis A Carey Dr., Robert M. Giuliano

Full solutions for Organic Chemistry, | 9th Edition

ISBN: 9780073402741

Organic Chemistry, | 9th Edition | ISBN: 9780073402741 | Authors: Francis A Carey Dr., Robert M. Giuliano

Solutions for Chapter 11.16: Benzylic Side Chains and Retrosynthetic Analysis

Solutions for Chapter 11.16
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This expansive textbook survival guide covers the following chapters and their solutions. This textbook survival guide was created for the textbook: Organic Chemistry, , edition: 9. Since 1 problems in chapter 11.16: Benzylic Side Chains and Retrosynthetic Analysis have been answered, more than 12418 students have viewed full step-by-step solutions from this chapter. Organic Chemistry, was written by Patricia and is associated to the ISBN: 9780073402741. Chapter 11.16: Benzylic Side Chains and Retrosynthetic Analysis includes 1 full step-by-step solutions.

Key Chemistry Terms and definitions covered in this textbook
  • Antibonding molecular orbital

    A molecular orbital in which electrons have a higher energy than they would in isolated atomic orbitals

  • bidentate ligand

    A ligand in which two linked coordinating atoms are bound to a metal. (Section 23.3)

  • branched polymer

    A polymer that contains a large number of branches connected to the main chain of the polymer.

  • Brønsted-Lowry base

    A proton acceptor

  • chemical equation.

    An equation that uses chemical symbols to show what happens during a chemical reaction. (3.7)

  • colligative properties.

    Properties of solutions that depend on the number of solute particles in solution and not on the nature of the solute particles. (12.6)

  • conrotatory

    In electrocyclic reactions,a type of rotation in which the orbitals being used to form the new s bond must rotate in the same way.

  • crown ether

    Cyclic polyethers whose molecular models resemble crowns.

  • diazotization

    The process of forming a diazonium salt by treating a primary amine with NaNO2 and HCl.

  • Double helix

    A type of secondary structure of DNA molecules in which two anti parallel polynucleotide strands are coiled in a right-handed manner about the same axis

  • irreversible process

    A process that cannot be reversed to restore both the system and its surroundings to their original states. Any spontaneous process is irreversible. (Section 19.1)

  • lock-and-key model

    A model of enzyme action in which the substrate molecule is pictured as fitting rather specifically into the active site on the enzyme. It is assumed that in being bound to the active site, the substrate is somehow activated for reaction. (Section 14.7)

  • mass spectrum

    In mass spectrometry,a plot that shows the relative abundance ofeach cation that was detected.

  • oxymercuration-demercuration

    A two-step process for the Markovnikov addition of water across an alkene. With this process, carbocation rearrangements do not occur.

  • paramagnetism

    A property that a substance possesses if it contains one or more unpaired electrons. A paramagnetic substance is drawn into a magnetic field. (Section 9.8)

  • S

    A term used to designate the configuration of a chirality center, determined in the following way: Each of the four groups is assigned a priority, and the molecule is then rotated (if necessary) so that the #4 group is directed behind the page (on a dash). A counterclockwise sequence for 1-2-3 is designated as S.

  • spin magnetic quantum number 1ms2

    A quantum number associated with the electron spin; it may have values of +12 or -12. (Section 6.7)

  • strong deactivators

    Groups that strongy deactivate an aromatic ring toward electrophilic aromatic substitution, thereby significantly decreasing the rate of the reaction.

  • torsional angle

    The angle between two groups in a Newman projection, also called the dihedral angle.

  • tosylate

    An excellent leaving group (OTs). transition state (Sect. 6.6): A state through which a reaction passes. On an energy diagram, a transition state corresponds with a local maximum.

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