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Solutions for Chapter 13.6: Interpreting 1 H NMR Spectra

Organic Chemistry, | 9th Edition | ISBN: 9780073402741 | Authors: Francis A Carey Dr., Robert M. Giuliano

Full solutions for Organic Chemistry, | 9th Edition

ISBN: 9780073402741

Organic Chemistry, | 9th Edition | ISBN: 9780073402741 | Authors: Francis A Carey Dr., Robert M. Giuliano

Solutions for Chapter 13.6: Interpreting 1 H NMR Spectra

This expansive textbook survival guide covers the following chapters and their solutions. Organic Chemistry, was written by and is associated to the ISBN: 9780073402741. Since 3 problems in chapter 13.6: Interpreting 1 H NMR Spectra have been answered, more than 31737 students have viewed full step-by-step solutions from this chapter. This textbook survival guide was created for the textbook: Organic Chemistry, , edition: 9. Chapter 13.6: Interpreting 1 H NMR Spectra includes 3 full step-by-step solutions.

Key Chemistry Terms and definitions covered in this textbook
  • acylium ion

    The resonancestabilized, cationic intermediate of a Friedel-Crafts acylation, formed by treating an acyl halide with aluminum trichloride.

  • alcohol

    An organic compound obtained by substituting a hydroxyl group 1¬OH2 for a hydrogen on a hydrocarbon. (Sections 2.9 and 24.4)

  • anomeric carbon

    The C1 position of the cyclic hemiacetal of an aldose or the C2 position of the cyclic hemiacetal of a ketose.

  • Aromatic compound

    A term used initially to classify benzene and its derivatives. More accurately, it is used to classify any compound that meets the Hückel criteria for aromaticity (Section 21.2A).

  • carbohydrates

    Polyhydroxy aldehydes or ketones with molecular formula CxH2xOx.

  • disulfide bridge

    The group that is formed when two cysteine residues of a polypeptide or protein are joined together.

  • donor atom

    The atom of a ligand that bonds to the metal. (Section 23.2)

  • E2

    A bimolecular b-elimination reaction.

  • Epoxide

    A cyclic ether in which oxygen is one atom of a three-membered ring

  • formal charge

    A charge associated with any atom that does not exhibit the appropriate number of valence electrons.

  • geminal

    Two groups connected to the same carbon atom. For example, a geminal dihalide is a compound with two halogens connected to the same carbon atom.

  • glycogen

    The general name given to a group of polysaccharides of glucose that are synthesized in mammals and used to store energy from carbohydrates. (Section 24.7)

  • half-reaction

    An equation for either an oxidation or a reduction that explicitly shows the electrons involved, for example, Zn2 + 1aq2 + 2 e- ¡ Zn1s2. (Section 20.2)

  • Homotopic groups

    Atoms or groups on an atom that give an achiral molecule when one of the groups is replaced by another group. The hydrogens of the CH2 group of propane, for example, are homotopic. Replacing either one of them with deuterium gives 2-deuteropropane, which is achiral. Homotopic groups have identical chemical shifts under all conditions

  • isoelectronic series

    A series of atoms, ions, or molecules having the same number of electrons. (Section 7.3)

  • lithium dialkyl cuprate

    A nucleophilic compound with the general structureR2CuLi.

  • mercapto group

    An SH group.

  • polycarbonates

    Polymers that are similar in structure to polyesters but with repeating carbonate groups (!O!CO2!) instead of repeating ester groups (!CO2!). polycyclic aromatic hydrocarbons

  • prosthetic group

    A nonprotein unit attached to a protein, such as heme in hemoglobin.

  • solid

    Matter that has both a definite shape and a definite volume. (Section 1.2)

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