Solutions for Chapter 14.7: Retrosynthetic Analysis and Grignard and Organolithium Reagents
Full solutions for Organic Chemistry, | 9th Edition
Solutions for Chapter 14.7: Retrosynthetic Analysis and Grignard and Organolithium ReagentsGet Full Solutions
An organic compound that has an NR2 group attached to a carbonyl. (Section 24.4)
A bond to a chair conformation of cyclohexane that extends from the ring parallel to the imaginary axis through the center of the ring; a bond that lies roughly perpendicular to the equator of the ring.
Benzyl group (C6H5CH2!)
The group derived from toluene by removing a hydrogen from its methyl group.
Valence electrons involved in forming a covalent bond (i.e., shared electrons).
A polymer that contains a large number of branches connected to the main chain of the polymer.
A tetrahedral carbon atom bearing four different groups.
A substance composed of atoms of two or more elements chemically united in fixed proportions. (1.4)
A polymer that is constructed from more than one repeating unit.
The angle by which two groups are separated in a Newman projection.
Carbohydrates comprisedof two monosaccharide units joined via aglycosidic linkage between the anomeric carbonof one monosaccharide and a hydroxyl group ofthe other monosaccharide.
A semiconducting material composed of just one element. (Section 12.7)
Energetic electromagnetic radiation emanating from the nucleus of a radioactive atom. (Section 21.1)
Naturally occurring compoundsthat can be extracted from cells usingnonpolar organic solvents.
The mass of the collection of atoms represented by the chemical formula for a molecule. (Section 3.3)
A reagent used for allylic bromination to avoid a competing reaction in which bromine adds across the p bond.
A solid whose dimensions range from 1 to 100 nm and whose properties differ from those of a bulk material with the same composition. (Section 12.1)
polar aprotic solvent
A solvent that lacks hydrogen atoms connected directly to an electronegative atom.
A particle with the same mass as an electron but with a positive charge, 0 +1e, or b+. (Section 21.1)
A term used to indicate that exactly three alkyl groups are attached directly to a particular position. For example, a tertiary carbocation has three alkyl groups attached directly to the electrophilic carbon atom (C+).
Valence-shell electron-pair repulsion (VSEPR)
A method for predicting bond angles based on the idea that electron pairs repel each other and keep as far apart as possible.