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Solutions for Chapter 16.10: Conversion of Vicinal Halohydrins to Epoxides

Organic Chemistry, | 9th Edition | ISBN: 9780073402741 | Authors: Francis A Carey Dr., Robert M. Giuliano

Full solutions for Organic Chemistry, | 9th Edition

ISBN: 9780073402741

Organic Chemistry, | 9th Edition | ISBN: 9780073402741 | Authors: Francis A Carey Dr., Robert M. Giuliano

Solutions for Chapter 16.10: Conversion of Vicinal Halohydrins to Epoxides

Solutions for Chapter 16.10
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Organic Chemistry, was written by and is associated to the ISBN: 9780073402741. Chapter 16.10: Conversion of Vicinal Halohydrins to Epoxides includes 1 full step-by-step solutions. This expansive textbook survival guide covers the following chapters and their solutions. This textbook survival guide was created for the textbook: Organic Chemistry, , edition: 9. Since 1 problems in chapter 16.10: Conversion of Vicinal Halohydrins to Epoxides have been answered, more than 25547 students have viewed full step-by-step solutions from this chapter.

Key Chemistry Terms and definitions covered in this textbook
  • Absorbance (A)

    A quantitative measure of the extent to which a compound absorbs radiation of a particular wavelength. A 5 log (I0/I ) where I0 is the incident radiation and I is the transmitted radiation

  • acidic cleavage

    A reaction in which bonds are broken in the presence of an acid. For example, in the presence of a strong acid, an ether is converted into two alkyl halides.

  • amino acid

    A carboxylic acid that contains an amino 1¬NH22 group attached to the carbon atom adjacent to the carboxylic acid 1¬COOH2 functional group. (Section 24.7)

  • anion.

    An ion with a net negative charge. (2.5)

  • Anti stereoselectivity

    The addition of atoms or groups of atoms to opposite faces of a carbon-carbon double bond.

  • Beer’s law

    In UV-Vis spectroscopy, an equation describing the relationship between molar absorptivity (e), absorbance (A), concentration (C), and path length (l): e = A (C Ž l)

  • Chain propagation

    A step in a chain reaction characterized by the reaction of a reactive intermediate and a molecule to give a new reactive intermediate and a new molecule.

  • chemical reactions

    Processes in which one or more substances are converted into other substances; also called chemical changes. (Section 1.3)

  • conjugated diene

    A compound inwhich two carbon-carbon p bonds are separated from each other by exactly one s bond.

  • Cycloaddition reaction

    A reaction in which two reactants add together in a single step to form a cyclic product. The best known of these is the Diels-Alder reaction

  • deshielded

    In NMR spectroscopy,protons or carbon atoms whose surrounding electron density is poor.

  • electrolytic cell

    A device in which a nonspontaneous oxidation–reduction reaction is caused to occur by passage of current under a sufficient external electrical potential. (Section 20.9)

  • Fischer projections

    A drawing style that is often used when dealing with compounds bearing multiple chirality centers, especially for carbohydrates. (See also Sect. 5.7.)

  • Fourier-transform NMR (FT-NMR)

    In nuclear magnetic resonance (NMR) spectroscopy, a technique in which the sample is irradiated with a short pulse that covers the entire range of relevant rf frequencies.

  • irreversible process

    A process that cannot be reversed to restore both the system and its surroundings to their original states. Any spontaneous process is irreversible. (Section 19.1)

  • Nucleophilic acyl substitution

    A reaction in which a nucleophile bonded to the carbon of an acyl group is replaced by another nucleophile.

  • phase diagram

    A graphic representation of the equilibria among the solid, liquid, and gaseous phases of a substance as a function of temperature and pressure. (Section 11.6)

  • Retrosynthesis

    A process of reasoning backwards from a target molecule to a suitable set of starting materials.

  • symmetry allowed

    A reaction that obeys conservation of orbital symmetry.

  • Syndiotactic polymer

    A polymer with alternating R and S confi gurations at the chiral centers along its chain, as, for example, syndiotactic polypropylene

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