- 220.127.116.11: Write the structure of the aminal or hemiaminal intermediate and th...
- 18.104.22.168: Not all biological reactions of amino acids involving imine interme...
- 22.214.171.124: The product of the following reaction is a heterocyclic aromatic co...
Solutions for Chapter 17.10: Reaction with Primary Amines: Imines
Full solutions for Organic Chemistry, | 9th Edition
Element in which the 5f orbitals are only partially occupied. (Section 6.8)
The basic unit of an element that can enter into chemical combination. (2.2)
A neutral molecule with nonadjacent positive and negative charges. An example of a betaine is the intermediate formed by addition of a Wittig reagent to an aldehyde or ketone
buffered solution (buffer)
A solution that undergoes a limited change in pH upon addition of a small amount of acid or base. (Section 17.2)
Confi gurational isomers
Isomers that differ by the confi guration of substituents on an atom. Refers to the arrangement of atoms about a stereocenter
A compound containing an electron-deficient atom that is capable of accepting a pair of electrons.
A polymer that isformed via anionic polymerization.
In a BaeyerVilliger oxidation, the migration rates of different groups, which determine the regiochemical outcome of the reaction.
molal boiling-point-elevation constant (Kb)
A constant characteristic of a particular solvent that gives the increase in boiling point as a function of solution molality: ?Tb = Kbm. (Section 13.5)
A reaction in which an acid and a base react in stoichiometrically equivalent amounts; the neutralization reaction between an acid and a metal hydroxide produces water and a salt. (Section 4.3)
Reactions that occur via a concerted process and do not involve either ionic or radical intermediates.
The conjugate base of phenol or a substituted phenol.
A reaction that occurs between substances in solution in which one of the products is insoluble. (Section 4.2)
primary alkyl halide
An organohalide in which the alpha (a) position is connected to only one alkyl group.
A six-membered cyclic hemiacetal form of a carbohydrate.
A mixture of equal amounts of two enantiomers.
An isotope that is radioactive; that is, it is undergoing nuclear changes with emission of radiation. (Section 21.1)
Atomic orbitals that are achieved by mathematically averaging one s orbital with two p orbitals to form three hybridized atomic orbitals.
Stork enamine synthesis
A Michaelreaction in which an enamine functions as anucleophile.
A solution to a set of equations that defi nes the energy of an electron in an atom and the region of space it may occupy.