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Solutions for Chapter 19.3: Nucleophilic Acyl Substitution Mechanisms

Organic Chemistry, | 9th Edition | ISBN: 9780073402741 | Authors: Francis A Carey Dr., Robert M. Giuliano

Full solutions for Organic Chemistry, | 9th Edition

ISBN: 9780073402741

Organic Chemistry, | 9th Edition | ISBN: 9780073402741 | Authors: Francis A Carey Dr., Robert M. Giuliano

Solutions for Chapter 19.3: Nucleophilic Acyl Substitution Mechanisms

Solutions for Chapter 19.3
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This expansive textbook survival guide covers the following chapters and their solutions. This textbook survival guide was created for the textbook: Organic Chemistry, , edition: 9. Chapter 19.3: Nucleophilic Acyl Substitution Mechanisms includes 1 full step-by-step solutions. Since 1 problems in chapter 19.3: Nucleophilic Acyl Substitution Mechanisms have been answered, more than 34624 students have viewed full step-by-step solutions from this chapter. Organic Chemistry, was written by and is associated to the ISBN: 9780073402741.

Key Chemistry Terms and definitions covered in this textbook
  • activated complex.

    The species temporarily formed by the reactant molecules as a result of the collision before they form the product. (13.4)

  • Allylic substitution

    Any reaction in which an atom or group of atoms is substituted for another atom or group of atoms at an allylic carbon.

  • amorphous solid.

    A solid that lacks a regular three-dimensional arrangement of atoms or molecules. (11.7)

  • degenerate

    Having the same energy.

  • Disulfide

    A molecule containing an !S!S! group

  • Enol

    A compound containing a hydroxyl group bonded to a doubly bonded carbon atom.

  • frequency

    The number of times per second that one complete wavelength passes a given point. (Section 6.1)

  • Homotopic groups

    Atoms or groups on an atom that give an achiral molecule when one of the groups is replaced by another group. The hydrogens of the CH2 group of propane, for example, are homotopic. Replacing either one of them with deuterium gives 2-deuteropropane, which is achiral. Homotopic groups have identical chemical shifts under all conditions

  • Ketone

    A compound containing a carbonyl group bonded to two carbons.

  • law of mass action

    The rules by which the equilibrium constant is expressed in terms of the concentrations of reactants and products, in accordance with the balanced chemical equation for the reaction. (Section 15.2)

  • low-spin complex

    A metal complex in which the electrons are paired in lower-energy orbitals. (Section 23.6)

  • mercapto group

    An SH group.

  • molecularity

    The number of molecules that participate as reactants in an elementary reaction. (Section 14.6)

  • nomenclature

    A system for naming organic compounds.

  • Pyranose

    A six-membered cyclic form of a monosaccharide.

  • secondary structure

    The manner in which a protein is coiled or stretched. (Section 24.7)

  • standard atmospheric pressure

    Defined as 760 torr or, in SI units, 101.325 kPa. (Section 10.2)

  • torsional strain

    The difference in energy between staggered and eclipsed conformations (for example, in ethane).

  • Valence-shell electron-pair repulsion (VSEPR)

    A method for predicting bond angles based on the idea that electron pairs repel each other and keep as far apart as possible.

  • wedge

    In bond-line structures, a group in front of the page.

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