Solutions for Chapter 21.13: The Hofmann Elimination

Organic Chemistry, | 9th Edition | ISBN: 9780073402741 | Authors: Francis A Carey Dr., Robert M. Giuliano

Full solutions for Organic Chemistry, | 9th Edition

ISBN: 9780073402741

Organic Chemistry, | 9th Edition | ISBN: 9780073402741 | Authors: Francis A Carey Dr., Robert M. Giuliano

Solutions for Chapter 21.13: The Hofmann Elimination

Solutions for Chapter 21.13
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This expansive textbook survival guide covers the following chapters and their solutions. Since 1 problems in chapter 21.13: The Hofmann Elimination have been answered, more than 12597 students have viewed full step-by-step solutions from this chapter. This textbook survival guide was created for the textbook: Organic Chemistry, , edition: 9. Chapter 21.13: The Hofmann Elimination includes 1 full step-by-step solutions. Organic Chemistry, was written by Patricia and is associated to the ISBN: 9780073402741.

Key Chemistry Terms and definitions covered in this textbook
  • Achiral

    An object that lacks chirality; an object that has no handedness

  • Allylic carbocation

    A carbocation in which an allylic carbon bears the positive charge.

  • beta (b) rays.

    Electrons. (2.2)

  • chain reaction

    A series of reactions in which one reaction initiates the next. (Section 21.7)

  • Charles’ and Gay-Lussac’s law.

    See Charles’ law.

  • Claisen rearrangement

    A [3,3] sigmatropic rearrangement that is observed for allylic vinylic ethers.

  • Confi gurational isomers

    Isomers that differ by the confi guration of substituents on an atom. Refers to the arrangement of atoms about a stereocenter

  • critical temperature

    The highest temperature at which it is possible to convert the gaseous form of a substance to a liquid. The critical temperature increases with an increase in the magnitude of intermolecular forces. (Section 11.4)

  • Crystalline domain

    An ordered crystalline region in the solid state of a polymer. Also called a crystallite.

  • Fourier transform NMR (FT-NMR)

    The modern NMR method that is based on a constant magnetic fi eld, a short pulse of electromagnetic radiation, and a mathematical Fourier transform to produce the spectrum

  • Haloform

    A compound of the type CHX3 where X is a halogen.

  • Hydrophobic effect

    The tendency of nonpolar groups to cluster so as to shield them from contact with an aqueous environment.

  • Mass spectrum

    A plot of the relative abundance of ions versus their mass-to-charge ratio

  • Order of precedence of functions

    A ranking of functional groups in order of priority for the purposes of IUPAC nomenclature.

  • paramagnetism

    A property that a substance possesses if it contains one or more unpaired electrons. A paramagnetic substance is drawn into a magnetic field. (Section 9.8)

  • photodissociation

    The breaking of a molecule into two or more neutral fragments as a result of absorption of light. (Section 18.2)

  • Polarimeter

    An instrument for measuring the ability of a compound to rotate the plane of plane-polarized light.

  • S

    A term used to designate the configuration of a chirality center, determined in the following way: Each of the four groups is assigned a priority, and the molecule is then rotated (if necessary) so that the #4 group is directed behind the page (on a dash). A counterclockwise sequence for 1-2-3 is designated as S.

  • Synstereoselective

    The addition of atoms or groups of atoms to the same face of a carbon-carbon double bond.

  • Wohl degradation

    A process that involves the removal of a carbon atom from an aldose. The aldehyde group is first converted to a cyanohydrin, followed by loss of HCN in the presence of a base.

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