- 18.104.22.168: N-Nitroso amines are stabilized by electron delocalization. Write t...
- 22.214.171.124: Nitrous acid deamination of 2,2-dimethylpropylamine, (CH3)3CCH2NH2,...
Solutions for Chapter 21.15: Nitrosation of Alkylamines
Full solutions for Organic Chemistry, | 9th Edition
A carboxylic acid that contains an amino 1¬NH22 group attached to the carbon atom adjacent to the carboxylic acid 1¬COOH2 functional group. (Section 24.7)
base ionization constant (Kb).
The equilibrium constant for the base ionization. (15.6)
See beta rays.
Polyhydroxy aldehydes or ketones with molecular formula CxH2xOx.
A state of dynamic balance in which the rate of formation of the products of a reaction from the reactants equals the rate of formation of the reactants from the products; at equilibrium the concentrations of the reactants and products remain constant. (Section 4.1;Chapter 15: Introduction)
A shift of an equilibrium induced by an ion common to the equilibrium. For example, added Na2SO4 decreases the solubility of the slightly soluble salt BaSO4, or added NaF decreases the percent ionization of HF. (Section 17.1)
crossed Claisen condensation
A Claisen condensation reaction that occurs between different partners.
Elimination of water.
delocalized molecular orbitals.
Molecular orbitals that are not confined between two adjacent bonding atoms but actually extend over three or more atoms. (10.8)
DEPT 13C NMR
In 13C NMR spectroscopy, a technique that utilizes two rf radiation emitters and provides information regarding the number of protons attached to each carbon atom in a compound.
A symbol used to show that structures on either side of it are resonance-contributing structures
An atom or group of atoms that imparts characteristic chemical properties to an organic compound. (Section 24.1)
glass transition temperature (Tg)
The temperature at which noncrystalline polymers become very soft.
High-density lipoprotein (HDL)
Plasma particles, density 1.06–1.21 g/mL, consisting of approximately 33% proteins, 30% cholesterol, 29% phospholipids, and 8% triglycerides.
A cyclic amide.
Solids that are composed of metal atoms. (Section 12.1)
A reaction that involves the participation of ions as reactants, intermediates, or products.
Primary structure of proteins
The sequence of amino acids in the polypeptide chain, read from the N-terminal amino acid to the C-terminal amino acid.
Any chemical species that contains one or more unpaired electrons.
A solution prepared by dissolving Ag2O in aqueous ammonia; used for selective oxidation of an aldehyde to a carboxylic acid.