- 24.24.17: The structures of each of the following are given within the chapte...
- 24.24.18: Identify the isoprene units in each of the following naturally occu...
- 24.24.19: Cubitene is a diterpene present in the defense secretion of a speci...
- 24.24.20: Pyrethrins are a group of naturally occurring insecticidal substanc...
- 24.24.21: Cerebrosides are found in the brain and in the myelin sheath of ner...
- 24.24.22: Each of the following reactions has been reported in the chemical l...
- 24.24.23: Describe an efficient synthesis of each of the following compounds ...
- 24.24.24: A synthesis of triacylglycerols has been described that begins with...
- 24.24.25: The isoprenoid compound shown is a scent marker present in the urin...
- 24.24.26: Sabinene is a monoterpene found in the oil of citrus fruits and pla...
- 24.24.27: Isoprene has sometimes been used as a starting material in the labo...
- 24.24.28: The ionones are fragrant substances present in the scent of iris an...
- 24.24.29: ,-Unsaturated steroidal ketones represented by the partial structur...
- 24.24.30: (a) Suggest a mechanism for the following reaction. H3PO4 (b) The f...
- 24.24.31: The following transformation was carried out as part of a multistep...
- 24.24.32: The glaucoma drug bimatoprost is synthesized in two steps from anot...
- 24.24.33: How many of the carbons come from acetate? From propanoate?
- 24.24.34: How many methylmalonates are involved in the biosynthesis of 6-deox...
- 24.24.35: (+)-Discodermolide (C33H55NO8) holds promise as an anticancer drug....
- 24.24.36: A key bond-forming step in the biosynthesis of naringenin chalcone ...
- 24.24.37: Carboncarbon bond formation in the 14-carbon polyketo chain is sugg...
- 24.24.38: Alternariol is a toxin produced by a mold that grows on agricultura...
Solutions for Chapter 24: Lipids
Full solutions for Organic Chemistry, | 9th Edition
A format for naming primary amines containing a complex alkyl group.
A group derived by removing a hydrogen from an alkane; given the symbol R!
atomic number (Z).
The number of protons in the nucleus of an atom. (2.3)
A conformation of cyclohexane in which all bond angles are fairly close to 109.5° and many hydrogen atoms are eclipsing each other.
A step in a chain reaction that involves destruction of reactive intermediates
A reaction in which a carbonyl group is completely reduced and replaced with two hydrogen atoms.
When signal splitting occurs in NMR spectroscopy, the distance between the individual peaks of a signal.
dissolving metal reduction
A reaction in which an alkyne is converted into a trans alkene.
A conformation about a carboncarbon single bond in which the atoms or groups on one carbon are as close as possible to the atoms or groups on an adjacent carbon.
The equilibrium established between reactant and product substances that are all in the same phase. (Section 15.4)
A polymer constructed from a single type of monomer.
In radical reactions, a type of arrow-pushing pattern in which a hydrogen atom is abstracted by a radical, generating a new radical.
An alloy in which smaller atoms fit into spaces between larger atoms. The larger atoms are metallic elements and the smaller atoms are typically nonmetallic elements. (Section 12.3)
l amino acid
Amino acids with Fischer projections that resemble the Fischer projections of l sugars.
The main fabricof cell membranes, assembled primarily fromphosphoglycerides.
In mass spectrometry, an odd molecular weight indicates an odd number of nitrogen atoms in the compound, while an even molecular weight indicates either an even number of nitrogen atoms or the absence of nitrogen.
A substance capable of dissociating more than one proton in water; H2SO4 is an example. (Section 16.6)
Common name for silicon dioxide. (Section 22.4)
A reaction that disobeys conservation of orbital symmetry.
An excellent leaving group (OTs). transition state (Sect. 6.6): A state through which a reaction passes. On an energy diagram, a transition state corresponds with a local maximum.
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