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Solutions for Chapter 25.7: Peptides
Full solutions for Organic Chemistry, | 9th Edition
The product obtainedfrom 1,2-addition across a conjugated p system.
A carbocation in which the positive charge is adjacent to a carbon-carbon double bond.
The study of the chemistry of living systems. (Chapter 24: Introduction)
When signal splitting occurs in NMR spectroscopy, the distance between the individual peaks of a signal.
Orbitals that have the same energy.
delocalized molecular orbitals.
Molecular orbitals that are not confined between two adjacent bonding atoms but actually extend over three or more atoms. (10.8)
For alkenes, a stereodescriptorthat indicates that the two priority groups are on opposite sides of the p bond.
A compound containing a hydroxyl group (OH) connected directly to a carbon-carbon double bond.
The point in a titration at which the added solute reacts completely with the solute present in the solution. (Section 4.6)
An alloy in which the components are not distributed uniformly; instead, two or more distinct phases with characteristic compositions are present. (Section 12.3)
Electrically charged atom or group of atoms (polyatomic ion); ions can be positively or negatively charged, depending on whether electrons are lost (positive) or gained (negative) by the atoms. (Section 2.7)
A common name for a thiol; that is, any compound that contains an -SH (sulfhydryl) group
A CH2 group.
The common name for bicyclo[2.2.1]heptane.
A C6H5 group.
For proteins, the sequence of amino acid residues.
An isotope that is radioactive; that is, it is undergoing nuclear changes with emission of radiation. (Section 21.1)
The general process of advancing scientific knowledge by making experimental observations and by formulating hypotheses, theories, and laws. (Section 1.3)
An excellent leaving group (OTs). transition state (Sect. 6.6): A state through which a reaction passes. On an energy diagram, a transition state corresponds with a local maximum.
Williamson ether synthesis
A method for preparing an ether from an alkoxide ion and an alkyl halide (via an SN2 process).