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Solutions for Chapter 17: Organic Chemistry 8th Edition

Organic Chemistry | 8th Edition | ISBN: 9780321768414 | Authors: L.G. Wade Jr

Full solutions for Organic Chemistry | 8th Edition

ISBN: 9780321768414

Organic Chemistry | 8th Edition | ISBN: 9780321768414 | Authors: L.G. Wade Jr

Solutions for Chapter 17

Solutions for Chapter 17
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Textbook: Organic Chemistry
Edition: 8
Author: L.G. Wade Jr
ISBN: 9780321768414

This expansive textbook survival guide covers the following chapters and their solutions. This textbook survival guide was created for the textbook: Organic Chemistry, edition: 8. Organic Chemistry was written by and is associated to the ISBN: 9780321768414. Chapter 17 includes 69 full step-by-step solutions. Since 69 problems in chapter 17 have been answered, more than 149383 students have viewed full step-by-step solutions from this chapter.

Key Chemistry Terms and definitions covered in this textbook
  • addition reactions

    Reactions that are characterized by the addition of two groups across a double bond. In the process, the pi (p) bond is broken.

  • Chromatography

    A separation method involving passing a vapor or solution mixture through a column packed with a material with different affi nities for different components of the mixture.

  • Clemmensen reduction

    Reduction of the C"O group of an aldehyde or ketone to a CH2 group using Zn(Hg) and HCl

  • crystallite

    A region of a polymer inwhich the chains are linearly extended and closein proximity to one another, resulting in van der Waals forces that hold the chains close together.

  • diffusion

    The spreading of one substance through a space occupied by one or more other substances. (Section 10.8)

  • elementary reaction

    A process in a chemical reaction that occurs in a single step. An overall chemical reaction consists of one or more elementary reactions or steps. (Section 14.6)

  • f-block metals

    Lanthanide and actinide elements in which the 4f or 5f orbitals are partially occupied. (Section 6.9)

  • Frequency

    The number of full cycles of a wave that pass a given point in a second, and reported in hertz (Hz), which has the units s21

  • Haloalkane (alkyl halide)

    A compound containing a halogen atom covalently bonded to an sp3 -hybridized carbon atom. Given the symbol R!X.

  • hydration

    A reaction in which a proton and a hydroxyl group (OH) are added across a p bond.

  • ignal splitting in NMR

    Spin-spin coupling with adjacent nuclei split NMR signals depending on the extent of coupling and the number of adjacent equivalent nuclei.

  • interstitial alloy

    An alloy in which smaller atoms fit into spaces between larger atoms. The larger atoms are metallic elements and the smaller atoms are typically nonmetallic elements. (Section 12.3)

  • Lindlar catalyst

    Finely powdered palladium metal deposited on solid calcium carbonate that has been specially modifi ed with lead salts. Its particular use is as a catalyst for the reduction of an alkyne to a cis alkene

  • Meisenheimer complex

    Theresonance-stabilized intermediate of a nucleophilicaromatic substitution reaction.

  • Molecular ion (M1)

    The radical cation formed by removal of a single electron from a parent molecule in a mass spectrometer.

  • N-glycoside

    The product obtained when a monosaccharide is treated with an amine in the presence of an acid catalyst.

  • Optical purity

    The specifi c rotation of a mixture of enantiomers divided by the specifi c rotation of the enantiomerically pure substance (expressed as a percent). Optical purity is numerically equal to enantiomeric excess, but experimentally determined.

  • polypeptide

    A polymer of amino acids that has a molecular weight of less than 10,000. (Section 24.7)

  • sodium cyanoborohydride

    A selective reducing agent (NaBH3CN) that can be used for reductive amination.

  • Staggered conformation

    A conformation about a carbon-carbon single bond in which the atoms or groups on one carbon are as far apart as possible from atoms or groups on an adjacent carbon.

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