- 10.10.1: Describe the separation of variables procedure as it is applied to ...
- 10.10.2: List and describe the significance of the quantum numbers needed to...
- 10.10.3: Specify and account for the selection rules for transitions in hydr...
- 10.10.4: Explain the significance of (a) a boundary surface and (b) the radi...
- 10.10.5: Outline the electron configurations of many-electron atoms in terms...
- 10.10.6: Describe and account for the variation of first ionization energies...
- 10.10.7: Describe the orbital approximation for the wavefunction of a manyel...
- 10.10.8: Explain the origin of spinorbit coupling and how it affects the app...
- 10.10.1(a): When ultraviolet radiation of wavelength 58.4 nm from a helium lamp...
- 10.10.1(b): When ultraviolet radiation of wavelength 58.4 nm from a helium lamp...
- 10.10.2(a): By differentiation of the 2s radial wavefunction, show that it has ...
- 10.10.2(b): By differentiation of the 3s radial wavefunction, show that it has ...
- 10.10.3(a): Locate the radial nodes in the 3s orbital of an H atom.
- 10.10.3(b): Locate the radial nodes in the 4p orbital of an H atom where, in th...
- 10.10.4(a): The wavefunction for the ground state of a hydrogen atom is Ner/a0....
- 10.10.4(b): The wavefunction for the 2s orbital of a hydrogen atom is N(2 r/a0)...
- 10.10.5(a): Calculate the average kinetic and potential energies of an electron...
- 10.10.5(b): Calculate the average kinetic and potential energies of a 2s electr...
- 10.10.6(a): Write down the expression for the radial distribution function of a...
- 10.10.6(b): Write down the expression for the radial distribution function of a...
- 10.10.7(a): Write down the expression for the radial distribution function of a...
- 10.10.7(b): Write down the expression for the radial distribution function of a...
- 10.10.8(a): What is the orbital angular momentum of an electron in the orbitals...
- 10.10.8(b): What is the orbital angular momentum of an electron in the orbitals...
- 10.10.9(a): Calculate the permitted values of j for (a) a d electron, (b) an f ...
- 10.10.9(b): Calculate the permitted values of j for (a) a p electron, (b) an h ...
- 10.10.10(a): An electron in two different states of an atom is known to have j =...
- 10.10.10(b): What are the allowed total angular momentum quantum numbers of a co...
- 10.10.11(a): State the orbital degeneracy of the levels in a hydrogen atom that ...
- 10.10.11(b): State the orbital degeneracy of the levels in a hydrogenic atom (Z ...
- 10.10.12(a): What information does the term symbol 1D2 provide about the angular...
- 10.10.12(b): What information does the term symbol 3F4 provide about the angular...
- 10.10.13(a): At what radius does the probability of finding an electron at a poi...
- 10.10.13(b): At what radius in the H atom does the radial distribution function ...
- 10.10.14(a): Which of the following transitions are allowed in the normal electr...
- 10.10.14(b): Which of the following transitions are allowed in the normal electr...
- 10.10.15(a): (a) Write the electronic configuration of the Ni2+ ion. (b) What ar...
- 10.10.15(b): (a) Write the electronic configuration of the V2+ ion. (b) What are...
- 10.10.16(a): Suppose that an atom has (a) 2, (b) 3 electrons in different orbita...
- 10.10.16(b): Suppose that an atom has (a) 4, (b) 5 electrons in different orbita...
- 10.10.17(a): What atomic terms are possible for the electron configuration ns1nd...
- 10.10.17(b): What atomic terms are possible for the electron configuration np1nd...
- 10.10.18(a): What values of J may occur in the terms (a) 1S, (b) 2P, (c) 3P? How...
- 10.10.18(b): What values of J may occur in the terms (a) 3D, (b) 4D, (c) 2G? How...
- 10.10.19(a): Give the possible term symbols for (a) Li [He]2s1, (b) Na [Ne]3p1.
- 10.10.19(b): Give the possible term symbols for (a) Sc [Ar]3d14s2, (b) Br [Ar]3d...
- 10.10.9: The Zeeman effect is the modification of an atomic spectrum by the ...
- 10.10.10: In 1976 it was mistakenly believed that the first of the superheavy...
- 10.10.11: What is the most probable point (not radius) at which a 2p electron...
- 10.10.12: Show by explicit integration that (a) hydrogenic 1s and 2s orbitals...
- 10.10.13: Explicit expressions for hydrogenic orbitals are given in Tables 10...
- 10.10.14: Determine whether the px and py orbitals are eigenfunctions of lz. ...
- 10.10.15: Show that lz and l2 both commute with the hamiltonian for a hydroge...
- 10.10.16: The size of an atom is sometimes considered to be measured by the r...
- 10.10.17: Some atomic properties depend on the average value of 1/r rather th...
- 10.10.18: One of the most famous of the obsolete theories of the hydrogen ato...
- 10.10.19: The Bohr model of the atom is specified in 10.18. What features of ...
- 10.10.20: Atomic units of length and energy may be based on the properties of...
- 10.10.21: Some of the selection rules for hydrogenic atoms were derived in Ju...
- 10.10.22: SternGerlach splittings of atomic beams are small and require eithe...
- 10.10.23: The wavefunction of a many-electron closed-shell atom can expressed...
- 10.10.24: Hydrogen is the most abundant element in all stars. However, neithe...
- 10.10.25: The distribution of isotopes of an element may yield clues about th...
- 10.10.26: Highly excited atoms have electrons with large principal quantum nu...
- 10.10.27: The spectrum of a star is used to measure its radial velocity with ...
- 10.10.28: The d-metals iron, copper, and manganese form cations with differen...
- 10.10.29: Thallium, a neurotoxin, is the heaviest member of Group 13 of the p...
Solutions for Chapter 10: Atomic structure and atomic spectra
Full solutions for Physical Chemistry | 8th Edition
ISBN: 9780716787594
Chapter 10: Atomic structure and atomic spectra includes 67 full step-by-step solutions. This textbook survival guide was created for the textbook: Physical Chemistry , edition: 8. Physical Chemistry was written by and is associated to the ISBN: 9780716787594. This expansive textbook survival guide covers the following chapters and their solutions. Since 67 problems in chapter 10: Atomic structure and atomic spectra have been answered, more than 228613 students have viewed full step-by-step solutions from this chapter.
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absolute zero
The lowest attainable temperature; 0 K on the Kelvin scale and -273.15 °C on the Celsius scale. (Section 1.4)
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acyl peroxide
A peroxide for which each oxygen atom is connected to an acyl group. Acyl peroxides are often used as radical initiators, because the O!O bond is especially weak.
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Bicycloalkane
An alkane containing two rings that share two carbons
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bond enthalpy
The enthalpy change, ?H, required to break a particular bond when the substance is in the gas phase. (Section 8.8)
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Diazonium ion
An ArN2 1 or RN2 1 ion
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electronegativity
A measure of the ability of an atom that is bonded to another atom to attract electrons to itself. (Section 8.4)
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Fingerprint region
Vibrations in the region 1500 to 400 cm21 of an IR spectrum are complex and diffi cult to analyze but are characteristic for different molecules.
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first order
A reaction that has a rate equation in which the sum of all exponents is one.
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Haworth projection
A way to view furanose and pyranose forms of monosaccharides. The ring is drawn fl at and most commonly viewed through its edge with the anomeric carbon on the right and the oxygen atom of the ring to the rear
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heat of fusion
The enthalpy change, ?H, for melting a solid. (Section 11.4)
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homogeneous catalyst
A catalyst that is in the same phase as the reactant substances. (Section 14.7)
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monomers
Molecules with low molecular weights, which can be joined together (polymerized) to form a polymer. (Section 12.8)
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organohalide
An organic compound containing at least one halogen.
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Sharpless asymmetric epoxidation
A reaction that converts an alkene into an epoxide via a stereospecific pathway.
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Tertiary structure of nucleic acids
The threedimensional arrangement of all atoms of a nucleic acid, commonly referred to as supercoiling
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Tesla (T)
The SI unit for magnetic fi eld strength.
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Thermoplastic
A polymer that can be melted and molded into a shape that is retained when it is cooled.
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twist boat
A conformation of cyclohexane that is lower in energy than a boat conformation but higher in energy than a chair conformation.
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Valence-shell electron-pair repulsion (VSEPR)
A method for predicting bond angles based on the idea that electron pairs repel each other and keep as far apart as possible.
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Zaitsev product
The more substituted product (alkene) of an elimination reaction.