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Solutions for Chapter 23: The Transition Elements and Their Coordination Compounds

Chemistry: The Molecular Nature of Matter and Change | 5th Edition | ISBN: 9780073048598 | Authors: Martin S. Silberberg

Full solutions for Chemistry: The Molecular Nature of Matter and Change | 5th Edition

ISBN: 9780073048598

Chemistry: The Molecular Nature of Matter and Change | 5th Edition | ISBN: 9780073048598 | Authors: Martin S. Silberberg

Solutions for Chapter 23: The Transition Elements and Their Coordination Compounds

Solutions for Chapter 23
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Textbook: Chemistry: The Molecular Nature of Matter and Change
Edition: 5
Author: Martin S. Silberberg
ISBN: 9780073048598

This expansive textbook survival guide covers the following chapters and their solutions. Since 144 problems in chapter 23: The Transition Elements and Their Coordination Compounds have been answered, more than 27624 students have viewed full step-by-step solutions from this chapter. This textbook survival guide was created for the textbook: Chemistry: The Molecular Nature of Matter and Change , edition: 5. Chemistry: The Molecular Nature of Matter and Change was written by and is associated to the ISBN: 9780073048598. Chapter 23: The Transition Elements and Their Coordination Compounds includes 144 full step-by-step solutions.

Key Chemistry Terms and definitions covered in this textbook
  • aldol addition reaction

    A reaction that occurs when an aldehyde or ketone is attacked by an enolate ion. The product of an aldol addition reaction is always a b-hydroxy aldehyde or ketone.

  • aldol condensation

    An aldol addition followed by dehydration to give an a,bunsaturated ketone or aldehyde.

  • alkoxide

    The conjugate base of an alcohol.

  • angle strain

    The increase in energy associated with a bond angle that has deviated from the preferred angle of 109.5°.

  • Aramid

    A polyaromatic amide; a polymer in which the monomer units are an aromatic diamine and an aromatic dicarboxylic acid

  • axial position

    For chair conformations of substituted cyclohexanes, a position that is parallel to a vertical axis passing through the center of the ring.

  • Basicity

    An equilibrium property measured by the position of equilibrium in an acid-base reaction, as, for example, the acid-base reaction between ammonia and water.

  • Born–Haber cycle

    A thermodynamic cycle based on Hess’s law that relates the lattice energy of an ionic substance to its enthalpy of formation and to other measurable quantities. (Section 8.2)

  • buffered solution (buffer)

    A solution that undergoes a limited change in pH upon addition of a small amount of acid or base. (Section 17.2)

  • Covalent bond

    A chemical bond formed between two atoms by sharing one or more pairs of electrons.

  • curved arrows

    Tools that are used for drawing resonance structures and for showing the flow of electron density during each step of a reaction mechanism.

  • Dalton’s law of partial pressures

    A law stating that the total pressure of a mixture of gases is the sum of the pressures that each gas would exert if it were present alone. (Section 10.6)

  • Diastereomers

    Stereoisomers that are not mirror images of each other; refers to relationships among two or more objects

  • diastereotopic

    Nonequivalent protons for which the replacement test produces diastereomers.

  • Frequency

    The number of full cycles of a wave that pass a given point in a second, and reported in hertz (Hz), which has the units s21

  • glycogen

    The general name given to a group of polysaccharides of glucose that are synthesized in mammals and used to store energy from carbohydrates. (Section 24.7)

  • octet rule

    The observation that second-row elements (C, N, O, and F) will form the necessary number of bonds so as to achieve a full valence shell (eight electrons).

  • Saponifi cation

    Hydrolysis of an ester in aqueous NaOH or KOH to an alcohol and the sodium or potassium salts of carboxylic acids

  • Stereoselective reaction

    A reaction in which one stereoisomer is formed in preference to all others. A stereoselective reaction may be enantioselective or diastereoselective, as the case may be.

  • Valence shell

    The outermost occupied electron shell of an atom.

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