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Solutions for Chapter 1.2: ClassIcal theorIes of chemIcal BondIng

Organic Chemistry | 6th Edition | ISBN: 9781936221349 | Authors: Marc Loudon, Jim Parise

Full solutions for Organic Chemistry | 6th Edition

ISBN: 9781936221349

Organic Chemistry | 6th Edition | ISBN: 9781936221349 | Authors: Marc Loudon, Jim Parise

Solutions for Chapter 1.2: ClassIcal theorIes of chemIcal BondIng

Since 7 problems in chapter 1.2: ClassIcal theorIes of chemIcal BondIng have been answered, more than 31435 students have viewed full step-by-step solutions from this chapter. Chapter 1.2: ClassIcal theorIes of chemIcal BondIng includes 7 full step-by-step solutions. Organic Chemistry was written by and is associated to the ISBN: 9781936221349. This expansive textbook survival guide covers the following chapters and their solutions. This textbook survival guide was created for the textbook: Organic Chemistry, edition: 6.

Key Chemistry Terms and definitions covered in this textbook
  • Bile acid

    A cholesterol-derived detergent molecule, such as cholic acid, which is secreted by the gallbladder into the intestine to assist in the absorption of dietary lipids.

  • Chain-transfer reaction

    The transfer of reactivity of an endgroup from one chain to another during a polymerization

  • chemical shift (d)

    In an NMR spectrum, the location of a signal, defined relative to the frequency of absorption of a reference compound, tetramethylsilane (TMS).

  • coordination number

    The number of adjacent atoms to which an atom is directly bonded. In a complex the coordination number of the metal ion is the number of donor atoms to which it is bonded. (Sections 12.37 and 24.2)

  • Dieckmann cyclization

    An intramolecular Claisen condensation.

  • Edman degradation

    A method for analyzing the sequence of amino acids in apeptide by removing one amino acid residue at a time and identifying each residue as it is removed.

  • enantiomer

    A nonsuperimposable mirror image.

  • Enantiotopic groups

    Atoms or groups on an atom that give a chiral center when one of the groups is replaced by another group. A pair of enantiomers results. The hydrogens of the CH2 group of ethanol, for example, are enantiotopic. Replacing one of them by deuterium gives (R)-1-deuteroethanol; replacing the other gives (S)-1-deuteroethanol. Enantiotopic groups have identical chemical shifts in achiral environments but different chemical shifts in chiral environments.

  • Haber process

    The catalyst system and conditions of temperature and pressure developed by Fritz Haber and coworkers for the formation of NH3 from H2 and N2. (Section 15.2)

  • HOMO

    The highest occupied molecular orbital.

  • Keto-enol tautomerism

    A type of isomerism involving keto (from ketone) and enol tautomers

  • lecithins

    Phosphoglycerides thatcontain choline.

  • mercurinium ion

    The intermediateformed during oxymercuration.

  • migratory aptitude

    In a BaeyerVilliger oxidation, the migration rates of different groups, which determine the regiochemical outcome of the reaction.

  • Polysaccharide

    A carbohydrate containing a large number of monosaccharide units, each joined to the next by one or more glycosidic bonds.

  • rotational motion

    Movement of a molecule as though it is spinning like a top. (Section 19.3)

  • secondary alkyl halide

    An organohalide in which the alpha (a) position is connected to exactly two alkyl groups.

  • sulfonate ions

    Common leaving groups. Examples include tosylate, mesylate, and triflate ions.

  • vicinal

    A term used to describe two identical groups attached to adjacent carbon atoms.

  • Wavenumbers (—n )

    The frequency of electromagnetic radiation expressed as the number of waves per centimeter, with units cm21 (read: reciprocal centimeters).

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