- 22.214.171.124: Draw an orbital interaction diagram corresponding to Fig. 1.14 for ...
- 126.96.36.199: The bond dissociation energy of H2 is 435 kJ mol1 (104 kcal mol1 );...
- 188.8.131.52: Referring to your solution to 1.17d, calculate the bond order of th...
Solutions for Chapter 1.8: AnothEr look At thE covAlEnt bond: MolEculAr orbitAlS
Full solutions for Organic Chemistry | 6th Edition
An elimination reaction in which a proton from the beta (b) position is removed together with the leaving group, forming a double bond.
An elementary step that involves two molecules. (13.5)
An intermediate containing a positively charged carbon atom.
Stereoisomers that are not mirror images of each other; refers to relationships among two or more objects
effective nuclear charge
The net positive charge experienced by an electron in a many-electron atom; this charge is not the full nuclear charge because there is some shielding of the nucleus by the other electrons in the atom. (Section 7.2)
A collection of orbitals that have the same value of n. For example, the orbitals with n = 3 (the 3s, 3p, and 3d orbitals) comprise the third shell. (Section 6.5)
A catalyst that is in the same phase as the reactant substances. (Section 14.7)
A polar group that has favorable interactions with water.
Points in a crystal all of which have identical environments. (Section 12.2)
The product of the mass, m, and velocity, v, of an object. (Section 6.4)
A reagent used for allylic bromination to avoid a competing reaction in which bromine adds across the p bond.
pH titration curve
A graph of pH as a function of added titrant. (Section 17.3)
A graphic representation of the equilibria among the solid, liquid, and gaseous phases of a substance as a function of temperature and pressure. (Section 11.6)
A measure of the force exerted on a unit area. In chemistry, pressure is often expressed in units of atmospheres (atm) or torr: 760 torr = 1 atm; in SI units pressure is expressed in pascals (Pa). (Section 10.2)
Reaction coordinate diagram
A graph showing the energy changes that occur during a chemical reaction; energy is plotted on the vertical axis and reaction progress is plotted on the horizontal axis.
An addition or substitution reaction in which one of two or more possible products is formed in preference to all others that might be formed.
The preferred metric units for use in science. (Section 1.4)
A bimolecular nucleophilic substitution reaction.
Compounds with the following structure: R!C#C!H
van der Waals forces
A group of intermolecular attractive forces including dipole-dipole, dipole-induced dipole, and induced dipole-induced dipole (dispersion) forces